Magnetic and structural properties of iron oxide nanoparticles produced by thermal decomposition of precursors in solution

R.R. Amirov ^a*, A.N. Solodov ^a**, R.M. Gataullina ^a***, J.R. Shaiymova ^a****, E.A. Burilova ^b*****,

A.G. Kiiamov ^a******, Y. Tyan ^a*******, R.G. Batulin ^a********, M.A. Cherosov ^a*********, D.A. Tayurskii ^a**********

^aKazan Federal University, Kazan, 420008 Russia

^bArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center,

Russian Academy of Sciences, Kazan, 420088 Russia

E-mail: ^*ramirov@kpfu.ru, ^**sanya.solodiv@live.com, ^***ramigataullina1999@gmail.com,

^****julia_shayimova@mail.ru, ^*****burilovajen07@mail.ru, ^******Airatphd@gmail.com,

^*******Rockland1922@hotmail.com, ^********tokamak@yandex.ru,

^*********Mcherosov@gmail.com, ^**********Dmitry.Tayurskii@kpfu.ru

Received December 20, 2022; Accepted January 23, 2023

ORIGINAL ARTICLE

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DOI: 10.26907/2542-064X.2023.1.5-22

For citation: Amirov R.R., Solodov A.N., Gataullina R.M., Shaiymova J.R., Burilova E.A., Kiiamov A.G., Tyan Y., Batulin R.G., Cherosov M.A., Taurskii D.A. Magnetic and structural properties of iron oxide nanoparticles produced by thermal decomposition of precursors in solution. Uchenye Zapiski Kazanskogo Universiteta. Seriya Estestvennye Nauki, 2023, vol. 165, no. 1, pp. 5–22. doi: 10.26907/2542-064X.2023.1.5-22. (In Russian)

Abstract

In this study, the method of thermal decomposition of iron(III) oleate at different ratios of oleic acid and octadecene-1 was used to obtain iron oxide nanoparticles (IONPs). Transmission electron microscopy (TEM) showed that they all had a spherical shape and a diameter of 8–9 nm, and FT-IR spectroscopy revealed the presence of oleate shells in them, which ensure the stability of the colloidal solutions of these nanoparticles in nonpolar solvents. For all synthesized IONPs, the sizes of the crystalline core formed by iron oxides were determined using X-ray diffraction analysis and magnetometry. The sizes of the oleate protective shells were established by comparison with the TEM data. These values were in agreement with those from the literature.

Keywords: iron oxide nanoparticles, Langevin model, transmission electron microscopy, powder X-ray diffraction analysis, magnetometry

Acknowledgements. IONPs synthesis and TEM studies were funded by the Russian Science Foundation (project no. 22-23-00348).

X-ray diffraction analysis and magnetometry measurements were supported by the Kazan Federal University Strategic Academic Leadership Program (PRIORITY-2030).

Figure Captions

Fig. 1. Characterization of the synthesized IONPs (nos. 1–3): a–c) TEM images of IONPs (nos. 1–3) with a 40-nm scale bar. The insets show the corresponding particle size distribution (scale to 20 nm) obtained by statistical analysis of approximately 3500 particles; d) IR spectra.

Fig. 2. Measured powder diffraction patterns of the studied samples of series 1 (black line), 2 (red line), and 3 (green line). The short vertical blue lines indicate the positions of the Fe₃O₄ iron oxide reflections.

Fig. 3. a–c) Dependence of the magnetization of samples nos. 1–3 on the external field at room temperature (black circles) and its approximation within the extended Langevin model (red line). d–f) Size distribution for samples nos. 1–3 obtained from M–H dependences.

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