KFU. Card publication. The Film Properties Obtained from Aniline by Plasma Deposition at Atmospheric Pressure

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FEDERAL UNIVERSITY

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THE FILM PROPERTIES OBTAINED FROM ANILINE BY PLASMA DEPOSITION AT ATMOSPHERIC PRESSURE

Form of presentation

Articles in international journals and collections

Year of publication

2024

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Authors, employees of KFU

Vakhitov Iskander Rashidovich, author

Kuklin Vladimir Aleksandrovich, author

Lunev Ivan Vladimirovich, author

Pudovkin Maksim Sergeevich, author

Other authors

Danilaev Maksim , author

Drobyshev Sergey , author

Karandashev Sergey , author

Bibliographic description in the original language

Danilaev, M. P., Vakhitov, I. R., Drobyshev, S. V., Lounev, I. V., Kamaliev, B. Z., Karandashov, S. A., ... & Pudovkin, M. S. (2023). The Film Properties Obtained from Aniline by Plasma Deposition at Atmospheric Pressure. Inorganic Materials: Applied Research, 14(3), 641-648.

Annotation

Abstract—The properties of polymer films obtained in plasma of barrier discharge at atmospheric pressure from aniline of amorphous form with simultaneous formation of carbon particles in the films were studied. The threshold of discharge energy density was established (~30 mJ/m), beginning from which a continuous film filled with agglomerates of carbon particles can be obtained. The structure of such films corresponds to the form typical of amorphous polymers. Carbon particles form agglomerates, the concentration of which weakly depends on the discharge energy density and constitutes ~(4–7) × 104 1/cm2, which does not allow increasing the conductivity. It was shown that the main contribution to the conductivity of films obtained from aniline and filled with carbon particles is made by the value of their moisture saturation. It was found that the creep of the material decreases with growth of the energy density, and hardness increases. This is associated with the formation and growth of the number of crosslinks in the samples with an increase in the energy input. The absolute values of Martens hardness correspond to the lower boundary for polyaniline, which is due to the small molecular weight of the obtained polymer.

Keywords

atmospheric pressure barrier discharge, carbon particles, conductivity

The name of the journal

Inorganic Materials: Applied Research

URL

https://link.springer.com/article/10.1134/S2075113323030103

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=294253&p_lang=2

Resource files

File name	Size (MB)	Format
F_Films_KAI_2023.pdf	1,01	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Vakhitov Iskander Rashidovich	ru_RU
dc.contributor.author	Kuklin Vladimir Aleksandrovich	ru_RU
dc.contributor.author	Lunev Ivan Vladimirovich	ru_RU
dc.contributor.author	Pudovkin Maksim Sergeevich	ru_RU
dc.contributor.author	Danilaev Maksim	ru_RU
dc.contributor.author	Drobyshev Sergey	ru_RU
dc.contributor.author	Karandashev Sergey	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Danilaev, M. P., Vakhitov, I. R., Drobyshev, S. V., Lounev, I. V., Kamaliev, B. Z., Karandashov, S. A., ... & Pudovkin, M. S. (2023). The Film Properties Obtained from Aniline by Plasma Deposition at Atmospheric Pressure. Inorganic Materials: Applied Research, 14(3), 641-648.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=294253&p_lang=2	ru_RU
dc.description.abstract	Inorganic Materials: Applied Research	ru_RU
dc.description.abstract	Abstract—The properties of polymer films obtained in plasma of barrier discharge at atmospheric pressure from aniline of amorphous form with simultaneous formation of carbon particles in the films were studied. The threshold of discharge energy density was established (~30 mJ/m), beginning from which a continuous film filled with agglomerates of carbon particles can be obtained. The structure of such films corresponds to the form typical of amorphous polymers. Carbon particles form agglomerates, the concentration of which weakly depends on the discharge energy density and constitutes ~(4–7) × 104 1/cm2, which does not allow increasing the conductivity. It was shown that the main contribution to the conductivity of films obtained from aniline and filled with carbon particles is made by the value of their moisture saturation. It was found that the creep of the material decreases with growth of the energy density, and hardness increases. This is associated with the formation and growth of the number of crosslinks in the samples with an increase in the energy input. The absolute values of Martens hardness correspond to the lower boundary for polyaniline, which is due to the small molecular weight of the obtained polymer.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	atmospheric pressure barrier discharge	ru_RU
dc.subject	carbon particles	ru_RU
dc.subject	conductivity	ru_RU
dc.title	The Film Properties Obtained from Aniline by Plasma Deposition at Atmospheric Pressure	ru_RU
dc.type	Articles in international journals and collections	ru_RU