Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
STUDY OF THE STRUCTURES OF THE TETRAGONAL PARAMAGNETIC CENTERS IN THE MIXED FLUORITE CRYSTALS WITH RARE-EARTH IONS BY EPR
Form of presentationArticles in international journals and collections
Year of publication2014
  • Aminov Linar Kashifovich, author
  • Gafurov Marat Revgerovich, author
  • Kurkin Igor Nikolaevich, author
  • Rodionov Aleksandr Aleksandrovich, author
  • Bibliographic description in the original language L. K. Aminov, M. R. Gafurov, I. N. Kurkin, A. A. Rodionov. Study of the Structures of the Tetragonal Paramagnetic Centers in the Mixed Fluorite Crystals with Rare-Earth Ions by EPR. Applied Magnetic Resonance 45(11), 1147-1156 (2014) DOI: 10.1007/s00723-014-0564-0
    Annotation Electron paramagnetic resonance (EPR) of the mixed fluorite crystals with the general formula (MeF2)1−x−y (REF3) x (RF3) y (Me = Ca, Sr, Ba; R = Y, La, Lu; RE?paramagnetic trivalent rare-earth ions) were studied comprehensively by different authors and several structural models of paramagnetic centers were considered. However, a lot of details of EPR spectra still remain unexplained. In this work some modifications of the simplest models are proposed which allow explaining adequately the variety of the tetragonal centers in crystals grown under the different conditions. The calculated from the proposed models components of g-factors for Ce3+, Nd3+, Sm3+, Er3+ ions are in a good agreement with the experimental values.
    Keywords Solid State Physics, Spectroscopy, Physical Chemistry
    The name of the journal APPL MAGN RESON
    URL http://link.springer.com/article/10.1007/s00723-014-0564-0
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=86573&p_lang=2

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