KFU. Card publication. Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange

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ANTI-SIEVE EFFECT IN GUEST INCLUSION BY THIACALIX[4]ARENE GIVING A SURGE IN THERMAL STABILITY OF ITS CLATHRATES PREPARED BY SOLID-PHASE GUEST EXCHANGE

Form of presentation

Articles in international journals and collections

Year of publication

2014

Authors, employees of KFU

Galyaltdinov Shamil Fazlurovich, author

Gorbachuk Valeriy Vilenovich, author

Ziganshin Marat Akhmedovich, author

Other authors

A.T. Gubaidullin; S.G. Vyshnevsky; O.I. Kalchenko.

Authors, postgraduates KFU

Galyaltdinov Shamil Fazlurovich, postgraduate kfu

Bibliographic description in the original language

V. Gorbatchuk, Sh. Galyaltdinov, M. Ziganshin, A. Gubaidullin, O. Kalchenko, S. Vyshnevsky // Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange // CrystEngComm. – 2014, 16 (18), 3781 - 3787

Annotation

CrystEngComm

Keywords

Thiacalixarene, clathrate, thermal stability, solid-phase exchange, X-ray powder diffractometry, anti-sieve effect.

The name of the journal

CrystEngComm

URL

http://pubs.rsc.org/en/Content/ArticleLanding/2014/CE/c3ce42304b#!divAbstract

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=86482&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Galyaltdinov Shamil Fazlurovich	ru_RU
dc.contributor.author	Gorbachuk Valeriy Vilenovich	ru_RU
dc.contributor.author	Ziganshin Marat Akhmedovich	ru_RU
dc.contributor.author	Galyaltdinov Shamil Fazlurovich	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	V. Gorbatchuk, Sh. Galyaltdinov, M. Ziganshin, A. Gubaidullin, O. Kalchenko, S. Vyshnevsky // Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange // CrystEngComm. – 2014, 16 (18), 3781 - 3787	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=86482&p_lang=2	ru_RU
dc.description.abstract	CrystEngComm	ru_RU
dc.description.abstract	CrystEngComm	ru_RU
dc.description.abstract	An unusual bell-like relationship between guest size parameter and properties of thiacalix[4]arene (1) clathrates was observed, which is a source of their very high thermal stability. For this, calixarene 1 clathrates were prepared in binary ?solid host ? guest vapor? system and by solid-phase exchange with guests of various molecular structure. The clathrates were studied by thermal analysis and X-ray powder diffractometry. Calixarene 1 was found to have a specific anti-sieve effect excluding smaller guest compounds, while having a preference for the larger ones. This effect may be avoided using solid-phase guest exchange in clathrate preparation, but it contributes much to the thermal stability of exchange products.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Thiacalixarene	ru_RU
dc.subject	clathrate	ru_RU
dc.subject	thermal stability	ru_RU
dc.subject	solid-phase exchange	ru_RU
dc.subject	X-ray powder diffractometry	ru_RU
dc.subject	anti-sieve effect.	ru_RU
dc.title	Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange	ru_RU
dc.type	Articles in international journals and collections	ru_RU