Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
SPECTROSCOPIC TECHNIQUES AND HINDERED MOLECULAR MOTION
Form of presentationInternational monographs
Year of publication2012
Языканглийский
  • Bashirov Ferid Israfilovich, author
  • Bibliographic description in the original language Ferid Bashirov. Spectroscopic techniques and hindered molecular motion. CRC Press, London – New York. – 2012. – 165 p.
    Annotation The united theoretical approach based on the extended angular jump model for the hindered molecular motion is used in order to describe the molecular spectra in single crystals, powders and liquids. The consecutive derivation of new analytical expressions describing quantitatively relative NMR-relaxation rates and intensities of homogeneously broadened spectral lines observed by dielectric, infrared, Raman, Rayleigh, and incoherent neutron spectroscopy techniques is presented. Accounting for two point symmetry groups, the symmetry group of the hindered molecular motion and that of the molecule site, distortion inclusively, enhances the power of the theory. The hindered molecular motion adapted to the crystallographic point symmetry groups handles the angular autocorrelation functions and, hence, the transformation property of molecular variables. Two dynamical quantities of the model, the symmetrized correlation times and the dynamical weights of hindered molecular motion states, expl
    Keywords Hindered molecular motion, molecular spectroscopy, group theory, condensed molecular media, angular autocorrelation function
    URL http://www.taylorandfrancis.com/books/details/9781439870839/
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=73292&p_lang=2
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