KFU. Card publication. Double-phase Nd3+, Yb3+:CeF3/CeO2 nanoparticles as potential materials for optical temperature sensing

KAZAN
FEDERAL UNIVERSITY

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DOUBLE-PHASE ND3+, YB3+:CEF3/CEO2 NANOPARTICLES AS POTENTIAL MATERIALS FOR OPTICAL TEMPERATURE SENSING

Form of presentation

Articles in international journals and collections

Year of publication

2024

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Authors, employees of KFU

Dokudovskaya Anna Konstantinovna, author

Korableva Stella Leonidovna, author

Morozov Oleg Aleksandrovich, author

Pudovkin Maksim Sergeevich, author

Rakhmatullin Rafail Mansurovich, author

Bibliographic description in the original language

Ginkel, A. K., Rakhmatullin, R. M., Morozov, O. A., & Pudovkin, M. S. (2024). Double-phase Nd3+, Yb3+: CeF3/CeO2 nanoparticles as potential materials for optical temperature sensing. Optical Materials, 116580.

Annotation

In this work, we study the possibility the use of Nd3+, Yb3+:CeF3/CeO2 nanoparticles in ratiometric luminescence thermometry. In order to explain the mechanism of the luminescence temperature sensitivity, we physically characterized the samples by means of transmission electron microscopy (TEM), X-ray diffraction (XRD), laser spectroscopy, and electron paramagnetic resonance (EPR). In particular, Nd3+, Yb3+:CeF3 nanoparticles were synthesized via co-precipitation method and annealed in air at 600 ◦C for 0, 15, 30, 60, and 120 min to obtain double-phase Nd3+, Yb3+:CeF3/CeO2 nanoparticles as well as single-phase Nd3+, Yb3+:CeO2 ones (at 120 min). The physical diameter of the samples gradually increases from 19 ? 2 (doped CeF3) to 409 ? 18 nm (doped CeO2). It was suggested, that the double-phase samples consist of sintered doped CeF3 and CeO2 nanoparticles having average grain diameter around 65 nm. The single-phase CeO2 sample also consists of sintered CeO2 nanoparticles, suggestively. The luminescence intensity ratio (LIR) was analyzed in the 80–320 K range (LIR = INd/IYb, where 848–925 nm (4F3/2 – 4I9/2) Nd3+ and 925–1048 nm (2F5/2 – 2F7/2) Yb3+). The maximal relative temperature sensitivity was achieved for Nd3+, Yb3+:CeO2 sample (~0.2 %/K), which is very competitive value. The LIR function has a simple linear temperature dependency in the broad 80–320 K which allows uniquely identifying the temperature at least in the studied broad temperature range. The mechanism of temperature sensitivity was suggested.

Keywords

Keywords: Luminescent thermometry Optical temperature sensing Nd3+/Yb3+ CeF3 CeO2

The name of the journal

Optical Materials

URL

https://www.sciencedirect.com/science/article/pii/S0925346724017634

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=308595&p_lang=2

Resource files

File name	Size (MB)	Format
F_Nd_Yb_CeF3_CeO2_Opt_Mat_2024.pdf	8,51	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Dokudovskaya Anna Konstantinovna	ru_RU
dc.contributor.author	Korableva Stella Leonidovna	ru_RU
dc.contributor.author	Morozov Oleg Aleksandrovich	ru_RU
dc.contributor.author	Pudovkin Maksim Sergeevich	ru_RU
dc.contributor.author	Rakhmatullin Rafail Mansurovich	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Ginkel, A. K., Rakhmatullin, R. M., Morozov, O. A., & Pudovkin, M. S. (2024). Double-phase Nd3+, Yb3+: CeF3/CeO2 nanoparticles as potential materials for optical temperature sensing. Optical Materials, 116580.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=308595&p_lang=2	ru_RU
dc.description.abstract	Optical Materials	ru_RU
dc.description.abstract	In this work, we study the possibility the use of Nd3+, Yb3+:CeF3/CeO2 nanoparticles in ratiometric luminescence thermometry. In order to explain the mechanism of the luminescence temperature sensitivity, we physically characterized the samples by means of transmission electron microscopy (TEM), X-ray diffraction (XRD), laser spectroscopy, and electron paramagnetic resonance (EPR). In particular, Nd3+, Yb3+:CeF3 nanoparticles were synthesized via co-precipitation method and annealed in air at 600 ◦C for 0, 15, 30, 60, and 120 min to obtain double-phase Nd3+, Yb3+:CeF3/CeO2 nanoparticles as well as single-phase Nd3+, Yb3+:CeO2 ones (at 120 min). The physical diameter of the samples gradually increases from 19 ? 2 (doped CeF3) to 409 ? 18 nm (doped CeO2). It was suggested, that the double-phase samples consist of sintered doped CeF3 and CeO2 nanoparticles having average grain diameter around 65 nm. The single-phase CeO2 sample also consists of sintered CeO2 nanoparticles, suggestively. The luminescence intensity ratio (LIR) was analyzed in the 80–320 K range (LIR = INd/IYb, where 848–925 nm (4F3/2 – 4I9/2) Nd3+ and 925–1048 nm (2F5/2 – 2F7/2) Yb3+). The maximal relative temperature sensitivity was achieved for Nd3+, Yb3+:CeO2 sample (~0.2 %/K), which is very competitive value. The LIR function has a simple linear temperature dependency in the broad 80–320 K which allows uniquely identifying the temperature at least in the studied broad temperature range. The mechanism of temperature sensitivity was suggested.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Double-phase Nd3+, Yb3+:CeF3/CeO2 nanoparticles as potential materials for optical temperature sensing	ru_RU
dc.type	Articles in international journals and collections	ru_RU