KFU. Card publication. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines

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FEDERAL UNIVERSITY

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2(5H)-FURANONE AZIDES IN THE SYNTHESIS OF IMINOPHOSPHORANES AND AMINES

Form of presentation

Articles in international journals and collections

Year of publication

2024

Язык

русский

Authors, employees of KFU

Islamov Daut Rinatovich, author

Kurbangalieva Almira Rafaelovna, author

Lodochnikova Olga Aleksandrovna, author

Saygitbatalova Elena Shiripovna, author

Usachev Konstantin Sergeevich, author

Fedorova Dilyara Rishatovna, author

Authors, students KFU

Shutilov Ilya Denisovich, author

Bibliographic description in the original language

Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847.

Annotation

The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring.

Keywords

2(5H)-furanone, unsaturated lactone, organic azide, iminophosphorane, Staudinger reaction, amine

The name of the journal

Russian Journal of General Chemistry

URL

https://link.springer.com/article/10.1134/S1070363224040108#citeas

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=301771&p_lang=2

Resource files

File name	Size (MB)	Format
Manuscript_RJGC_2024_PDF.docx.pdf	0,95	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Islamov Daut Rinatovich	ru_RU
dc.contributor.author	Kurbangalieva Almira Rafaelovna	ru_RU
dc.contributor.author	Lodochnikova Olga Aleksandrovna	ru_RU
dc.contributor.author	Saygitbatalova Elena Shiripovna	ru_RU
dc.contributor.author	Usachev Konstantin Sergeevich	ru_RU
dc.contributor.author	Fedorova Dilyara Rishatovna	ru_RU
dc.contributor.author	Shutilov Ilya Denisovich	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Saigitbatalova E.S. 2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines / E.S. Saigitbatalova, D.R. Fedorova, O.A. Lodochnikova, D. R. Islamov , I. D. Shutilov , K. S. Usachev, A. R. Kurbangalieva // Russ J Gen Chem - 2024. 94, p 835–847.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=301771&p_lang=2	ru_RU
dc.description.abstract	Russian Journal of General Chemistry	ru_RU
dc.description.abstract	The synthesis and characterization of previously unknown azides, iminophosphoranes and amines from commercially available mucochloric and mucobromic acids is reported. The reaction of 5-alkoxy-3,4-dihalo-2(5H)-furanones with sodium azide resulted in the regioselective formation of furanone 4-azidoderivatives. A series of novel iminophosphoranes was obtained from the reaction of corresponding azides with triphenylphosphine. Reduction of iminophosphoranes with stannous chloride dihydrate led to the heterocycles, possessing an amino group at the C4 carbon atom of the unsaturated γ-lactone ring.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	2(5H)-furanone	ru_RU
dc.subject	unsaturated lactone	ru_RU
dc.subject	organic azide	ru_RU
dc.subject	iminophosphorane	ru_RU
dc.subject	Staudinger reaction	ru_RU
dc.subject	amine	ru_RU
dc.title	2(5H)-Furanone Azides in the Synthesis of Iminophosphoranes and Amines	ru_RU
dc.type	Articles in international journals and collections	ru_RU