KFU. Card publication. The Analytical Capabilities of Electrochemical Sensors Based on Transition Metal Oxide Nanomaterials

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FEDERAL UNIVERSITY

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THE ANALYTICAL CAPABILITIES OF ELECTROCHEMICAL SENSORS BASED ON TRANSITION METAL OXIDE NANOMATERIALS

Form of presentation

Articles in international journals and collections

Year of publication

2023

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Authors, employees of KFU

Ziyatdinova Guzel Kamilevna, author

Authors, postgraduates KFU

Gimadutdinova Liliya Timurovna, postgraduate kfu

Yakupova Elvira Nailevna, postgraduate kfu

Authors, students KFU

Antonova Tatyana Sergeevna, author

Grigoreva Irina Olegovna, author

Bibliographic description in the original language

Ziyatdinova, G. The analytical capabilities of electrochemical sensors based on transition metal oxide nanomaterials / G. Ziyatdinova, L. Gimadutdinova, T. Antonova, I. Grigoreva, E. Yakupova // Eng. Proc. - 2023. - V. 48. - � 1. - Article 13. - 7 p.

Annotation

Voltammetric sensors based on CeO2, SnO2, CeO2?Fe2O3 nanoparticles (NPs) and MnO2 nanorods (NRs) were developed for the quantification of various organic substances. Surfactant media were applied as dispersive agents for metal oxide nanomaterials, providing a high stability of the dispersions after sonication and a decrease in the NPs' size, as well as the preconcentration of the target analytes at the sensor surface due to the hydrophobic interactions between the surfactant and the analyte molecules. Natural phenolics (quercetin, rutin, gallic acid, taxifolin, eugenol, vanillin, and hesperidin), propyl gallate, α-lipoic acid, and synthetic food colorants (tartrazine, brilliant blue FCF, and sudan I) were studied as analytes. The effect of the nature and concentration of the surfactant on the target analyte response was evaluated. Cationic surfactants (cetylpyridinium (CPB) or cetyltriphenylphosphonium bromides (CTPPB)) showed the best effect for the majority of the analytes. Wide linear dynamic ranges and low detection limits were obtained and were improved vs. reported to date. The simultaneous quantification of tartrazine and brilliant blue FCF was achieved with a high selectivity. The practical applicability of the sensors was shown on the real samples and was validated by comparison to independent methods.

Keywords

Electrochemical sensors, voltammetry, chemically modified electrodes, metal oxide nanomaterials, surfactants, antioxidants, food colorants, azo dyes

The name of the journal

Engineering Proceedings

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85184658375&doi=10.3390%2fCSAC2023-14916&partnerID=40&md5=9246be80ea52bd6f7ab0140f1afc5cf2

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=300055&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Antonova Tatyana Sergeevna	ru_RU
dc.contributor.author	Grigoreva Irina Olegovna	ru_RU
dc.contributor.author	Gimadutdinova Liliya Timurovna	ru_RU
dc.contributor.author	Yakupova Elvira Nailevna	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Ziyatdinova, G. The analytical capabilities of electrochemical sensors based on transition metal oxide nanomaterials / G. Ziyatdinova, L. Gimadutdinova, T. Antonova, I. Grigoreva, E. Yakupova // Eng. Proc. - 2023. - V. 48. - � 1. - Article 13. - 7 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=300055&p_lang=2	ru_RU
dc.description.abstract	Engineering Proceedings	ru_RU
dc.description.abstract	Voltammetric sensors based on CeO2, SnO2, CeO2?Fe2O3 nanoparticles (NPs) and MnO2 nanorods (NRs) were developed for the quantification of various organic substances. Surfactant media were applied as dispersive agents for metal oxide nanomaterials, providing a high stability of the dispersions after sonication and a decrease in the NPs' size, as well as the preconcentration of the target analytes at the sensor surface due to the hydrophobic interactions between the surfactant and the analyte molecules. Natural phenolics (quercetin, rutin, gallic acid, taxifolin, eugenol, vanillin, and hesperidin), propyl gallate, α-lipoic acid, and synthetic food colorants (tartrazine, brilliant blue FCF, and sudan I) were studied as analytes. The effect of the nature and concentration of the surfactant on the target analyte response was evaluated. Cationic surfactants (cetylpyridinium (CPB) or cetyltriphenylphosphonium bromides (CTPPB)) showed the best effect for the majority of the analytes. Wide linear dynamic ranges and low detection limits were obtained and were improved vs. reported to date. The simultaneous quantification of tartrazine and brilliant blue FCF was achieved with a high selectivity. The practical applicability of the sensors was shown on the real samples and was validated by comparison to independent methods.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Electrochemical sensors	ru_RU
dc.subject	voltammetry	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	metal oxide nanomaterials	ru_RU
dc.subject	surfactants	ru_RU
dc.subject	antioxidants	ru_RU
dc.subject	food colorants	ru_RU
dc.subject	azo dyes	ru_RU
dc.title	The Analytical Capabilities of Electrochemical Sensors Based on Transition Metal Oxide Nanomaterials	ru_RU
dc.type	Articles in international journals and collections	ru_RU