KFU. Card publication. Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5.

KAZAN
FEDERAL UNIVERSITY

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DIVERGENT SYNTHESIS OF OXAPHOSPHOLENES AND PHOSPHACOUMARINES VIA THE REACTION OF 2-ALKENYLPHENOLS WITH PCL3 OR PCL5.

Form of presentation

Articles in international journals and collections

Year of publication

2024

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Authors, employees of KFU

Mironov Vladimir Fedorovich, author

Tatarinov Dmitriy Anatolevich, author

Khayarov Khasan Rafaelevich, author

Authors, postgraduates KFU

Mikulenkova Elina Aleksandrovna, postgraduate kfu

Bibliographic description in the original language

D.A.Tatarinov, E.A.Mikulenkova, I.Litvinov, K.Khayarov and V.F.Mironov. Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5. // Org. Biomol. Chem. 2024. Vol. 22. No. 8. P. 1629-1633. Doi 10.1039/D3OB01718D.

Annotation

The divergent synthesis of benzo[e]-1,2-oxaphosphinines or benzo[d]-1,2-oxaphospholenes along with spirocyclic quasiphosphonium compounds based on 2-alkenylphenols and phosphorus(III/V) chlorides is presented. The reaction is condition-dependent and determined by the biphility of the phosphorus(III) derivative and the dual reactivity of 2-alkenylphenol. The procedures are applicable for obtaining benzo[e]-1,2-oxaphosphinines substituted at position 4 and disubstituted at positions 4 and 5 as well as 3,3-disubstituted benzo[d]-1,2-oxaphospholenes with good to high yields.

Keywords

2-alkenylphenols, oxaphosphinines, oxaphospholenes, divergent synthesis, quasiphosphonium compounds

The name of the journal

Organic and Biomolecular Chemistry

URL

https://pubs.rsc.org/en/Content/ArticleLanding/2023/OB/D3OB01718D

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=296067&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Mironov Vladimir Fedorovich	ru_RU
dc.contributor.author	Tatarinov Dmitriy Anatolevich	ru_RU
dc.contributor.author	Khayarov Khasan Rafaelevich	ru_RU
dc.contributor.author	Mikulenkova Elina Aleksandrovna	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	D.A.Tatarinov, E.A.Mikulenkova, I.Litvinov, K.Khayarov and V.F.Mironov. Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5. // Org. Biomol. Chem. 2024. Vol. 22. No. 8. P. 1629-1633. Doi 10.1039/D3OB01718D.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=296067&p_lang=2	ru_RU
dc.description.abstract	Organic and Biomolecular Chemistry	ru_RU
dc.description.abstract	The divergent synthesis of benzo[e]-1,2-oxaphosphinines or benzo[d]-1,2-oxaphospholenes along with spirocyclic quasiphosphonium compounds based on 2-alkenylphenols and phosphorus(III/V) chlorides is presented. The reaction is condition-dependent and determined by the biphility of the phosphorus(III) derivative and the dual reactivity of 2-alkenylphenol. The procedures are applicable for obtaining benzo[e]-1,2-oxaphosphinines substituted at position 4 and disubstituted at positions 4 and 5 as well as 3,3-disubstituted benzo[d]-1,2-oxaphospholenes with good to high yields.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	2-alkenylphenols	ru_RU
dc.subject	oxaphosphinines	ru_RU
dc.subject	oxaphospholenes	ru_RU
dc.subject	divergent synthesis	ru_RU
dc.subject	quasiphosphonium compounds	ru_RU
dc.title	Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5.	ru_RU
dc.type	Articles in international journals and collections	ru_RU