KFU. Card publication. New Multifunctional Synthon in Organic Chemistry

KAZAN
FEDERAL UNIVERSITY

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NEW MULTIFUNCTIONAL SYNTHON IN ORGANIC CHEMISTRY

Form of presentation

Articles in international journals and collections

Year of publication

2022

Язык

английский

Authors, employees of KFU

Grishaev Denis Yurevich, author

Other authors

Andreeva Vera Vladimirovna, author

Ivanova Elizaveta Sergeevna, author

Maryasov Maksim Aleksandrovich, author

Nasakin Oleg Evgenevich, author

Bibliographic description in the original language

Nasakin O. E. New Multifunctional Synthon in Organic Chemistry / O. E. Nasakin, E. S. Ivanova, M. A. Marya-sov, V. V. Andreeva, O. A. Lodochnikova, D. Yu. Grishaev // SSRN.-2022.-P.17

Annotation

SSRN

Keywords

unsymmetrical dimethylhydrazine, methylene dimethylhydrazone, tetracyanoethylene, tetracyanoketones, Thorp-Ziegler type cyclization

The name of the journal

SSRN

URL

https://ssrn.com/abstract=4272817 or http://dx.doi.org/10.2139/ssrn.4272817

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=295505&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Grishaev Denis Yurevich	ru_RU
dc.contributor.author	Andreeva Vera Vladimirovna	ru_RU
dc.contributor.author	Ivanova Elizaveta Sergeevna	ru_RU
dc.contributor.author	Maryasov Maksim Aleksandrovich	ru_RU
dc.contributor.author	Nasakin Oleg Evgenevich	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Nasakin O. E. New Multifunctional Synthon in Organic Chemistry / O. E. Nasakin, E. S. Ivanova, M. A. Marya-sov, V. V. Andreeva, O. A. Lodochnikova, D. Yu. Grishaev // SSRN.-2022.-P.17	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=295505&p_lang=2	ru_RU
dc.description.abstract	SSRN	ru_RU
dc.description.abstract	“Heptyl” (unsymmetrical dimethylhydrazine - UDMH) is actively used as fuel for rocket engines in many countries around the world. Nonetheless, it constantly loses its properties due to absorption of moisture which cannot be azeotroped. Its long term application is of special concern. UDMH's transportation and processing is complicated since it is an extremely toxic compound of the 1 st hazard class. Its disposal via burning gives much more toxic oxidation products. The safest way to neutralize it is instantaneous interaction with formalin solution to form less toxic 1,1-dimethyl-2-methylenehydrazone (MDH), which is polymerized in an acidic media, and the resulting product is burned forming a huge amount of nitrogen oxides. The purpose of this work is to reveal the synthetic possibilities and practical application of MDH. We would like to pay international chemical community's attention to this extremely promising metastable compound to the purposes of molecular design, pharmaceutical and medicinal chemistry.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	unsymmetrical dimethylhydrazine	ru_RU
dc.subject	methylene dimethylhydrazone	ru_RU
dc.subject	tetracyanoethylene	ru_RU
dc.subject	tetracyanoketones	ru_RU
dc.subject	Thorp-Ziegler type cyclization	ru_RU
dc.title	New Multifunctional Synthon in Organic Chemistry	ru_RU
dc.type	Articles in international journals and collections	ru_RU