KFU. Card publication. Crystal structure refinement, low- and high temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit

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CRYSTAL STRUCTURE REFINEMENT, LOW- AND HIGH TEMPERATURE X-RAY DIFFRACTION AND MöSSBAUER SPECTROSCOPY STUDY OF THE OXOBORATE LUDWIGITE FROM THE ITEN'YURGINSKOE DEPOSIT

Form of presentation

Articles in international journals and collections

Year of publication

2023

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Authors, employees of KFU

Vagizov Farit Gabdulkhakovich, author

Zinnatullin Almaz Linarovich, author

Bibliographic description in the original language

Biryukov, Y.P. Crystal structure refinement, low- and high temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit / Biryukov, Y.P., Zinnatullin, A.L., Levashova, I.O., Vagizov F,...Filatov, S.K., Pekov, I.V. // Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, - 2023, - V. 79, - p. 368–379

Annotation

his paper reports an investigation of the chemistry, crystal structure refinement and thermal behavior (80–1650 K) of ludwigite from the Iten'yurginskoe deposit (Eastern Chukotka, Russia). Its chemical composition was determined by electron microprobe analysis, giving an empirical formula (Mg1.70Fe2+0.29Mn0.01)Σ2.00(Fe3+0.90Al0.08Mg0.02)Σ1.00O2(BO3). A refinement of the crystal structure from single-crystal X-ray diffraction data (SCXRD) was provided for the first time for ludwigite from this deposit (R = 0.047). The structure can be described as a framework composed of [MO6]n− octahedra and isolated [BO3]3− triangles located in triangular interstices of the framework. Based on a comprehensive analysis of SCXRD and Mössbauer spectroscopy data, the M1 site is occupied by Mg, M2 and M3 by Mg and Fe2+, M4 by Fe3+, Mg and Al.

Keywords

oxoborate, ludwigite, crystal structure, Mossbauer spectroscopy, in situ methods, oxidation, thermal expansion, Iten'yurginskoe deposit

The name of the journal

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

URL

https://doi.org/10.1107/S2052520623006455

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=290738&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Vagizov Farit Gabdulkhakovich	ru_RU
dc.contributor.author	Zinnatullin Almaz Linarovich	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Biryukov, Y.P. Crystal structure refinement, low- and high temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit / Biryukov, Y.P., Zinnatullin, A.L., Levashova, I.O., Vagizov F,...Filatov, S.K., Pekov, I.V. // Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, - 2023, - V. 79, - p. 368–379	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=290738&p_lang=2	ru_RU
dc.description.abstract	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials	ru_RU
dc.description.abstract	his paper reports an investigation of the chemistry, crystal structure refinement and thermal behavior (80–1650 K) of ludwigite from the Iten'yurginskoe deposit (Eastern Chukotka, Russia). Its chemical composition was determined by electron microprobe analysis, giving an empirical formula (Mg1.70Fe2+0.29Mn0.01)Σ2.00(Fe3+0.90Al0.08Mg0.02)Σ1.00O2(BO3). A refinement of the crystal structure from single-crystal X-ray diffraction data (SCXRD) was provided for the first time for ludwigite from this deposit (R = 0.047). The structure can be described as a framework composed of [MO6]n− octahedra and isolated [BO3]3− triangles located in triangular interstices of the framework. Based on a comprehensive analysis of SCXRD and Mössbauer spectroscopy data, the M1 site is occupied by Mg, M2 and M3 by Mg and Fe2+, M4 by Fe3+, Mg and Al.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	oxoborate	ru_RU
dc.subject	ludwigite	ru_RU
dc.subject	crystal structure	ru_RU
dc.subject	Mossbauer spectroscopy	ru_RU
dc.subject	in situ methods	ru_RU
dc.subject	oxidation	ru_RU
dc.subject	thermal expansion	ru_RU
dc.subject	Iten'yurginskoe deposit	ru_RU
dc.title	Crystal structure refinement, low- and high temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit	ru_RU
dc.type	Articles in international journals and collections	ru_RU