KFU. Card publication. Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows

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FEDERAL UNIVERSITY

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ND3+, YB3+: YF3 OPTICAL TEMPERATURE NANOSENSORS OPERATING IN THE BIOLOGICAL WINDOWS

Form of presentation

Articles in international journals and collections

Year of publication

2022

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Authors, employees of KFU

Gafurov Marat Revgerovich, author

Kiyamov Ayrat Gazinurovich, author

Oleynikova Ekaterina Ilinichna, author

Pudovkin Maksim Sergeevich, author

Cherosov Mikhail Andreevich, author

Bibliographic description in the original language

Pudovkin, M., Oleynikova, E., Kiiamov, A., Cherosov, M., & Gafurov, M. (2022). Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows. Materials, 16(1), 39.

Annotation

This work is devoted to the study of thermometric performances of Nd3+ (0.1 or 0.5 mol.%), Yb3+ (X%):YF3 nanoparticles. Temperature sensitivity of spectral shape is related to the phonon-assisted nature of energy transfer (PAET) between Nd3+ and Yb3+). However, in the case of single-doped Nd3+ (0.1 or 0.5 mol.%):YF3 nanoparticles, luminescence decay time (LDT) of 4F3/2 level of Nd3+ in Nd3+ (0.5 mol.%):YF3 decreases with the temperature decrease. In turn, luminescence decay time in Nd3+ (0.1 mol.%):YF3 sample remains constant. It was proposed, that at 0.5 mol.% the cross-relaxation (CR) between Nd3+ ions takes place in contradistinction from 0.1 mol.% Nd3+ concentration. The decrease of LDT with temperature is explained by the decrease of distances between Nd3+ with temperature that leads to the increase of cross-relaxation efficiency. It was suggested, that the presence of both CR and PAET processes in the studied system (Nd3+ (0.5 mol.%), Yb3+ (X%):YF3) nanoparticles provides higher temperature sensitivity compared to the systems having one process (Nd3+ (0.1 mol.%), Yb3+ (X%):YF3). The experimental results confirmed this suggestion. The maximum relative temperature sensitivity was 0.9%?K−1 at 80 K.

Keywords

lifetime thermometry; Nd3+, Yb3+:YF3; optical temperature sensors

The name of the journal

Materials

URL

https://www.mdpi.com/1996-1944/16/1/39

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=274925&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gafurov Marat Revgerovich	ru_RU
dc.contributor.author	Kiyamov Ayrat Gazinurovich	ru_RU
dc.contributor.author	Oleynikova Ekaterina Ilinichna	ru_RU
dc.contributor.author	Pudovkin Maksim Sergeevich	ru_RU
dc.contributor.author	Cherosov Mikhail Andreevich	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Pudovkin, M., Oleynikova, E., Kiiamov, A., Cherosov, M., & Gafurov, M. (2022). Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows. Materials, 16(1), 39.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=274925&p_lang=2	ru_RU
dc.description.abstract	Materials	ru_RU
dc.description.abstract	This work is devoted to the study of thermometric performances of Nd3+ (0.1 or 0.5 mol.%), Yb3+ (X%):YF3 nanoparticles. Temperature sensitivity of spectral shape is related to the phonon-assisted nature of energy transfer (PAET) between Nd3+ and Yb3+). However, in the case of single-doped Nd3+ (0.1 or 0.5 mol.%):YF3 nanoparticles, luminescence decay time (LDT) of 4F3/2 level of Nd3+ in Nd3+ (0.5 mol.%):YF3 decreases with the temperature decrease. In turn, luminescence decay time in Nd3+ (0.1 mol.%):YF3 sample remains constant. It was proposed, that at 0.5 mol.% the cross-relaxation (CR) between Nd3+ ions takes place in contradistinction from 0.1 mol.% Nd3+ concentration. The decrease of LDT with temperature is explained by the decrease of distances between Nd3+ with temperature that leads to the increase of cross-relaxation efficiency. It was suggested, that the presence of both CR and PAET processes in the studied system (Nd3+ (0.5 mol.%), Yb3+ (X%):YF3) nanoparticles provides higher temperature sensitivity compared to the systems having one process (Nd3+ (0.1 mol.%), Yb3+ (X%):YF3). The experimental results confirmed this suggestion. The maximum relative temperature sensitivity was 0.9%?K−1 at 80 K.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	lifetime thermometry; Nd3+	ru_RU
dc.subject	Yb3+:YF3; optical temperature sensors	ru_RU
dc.title	Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows	ru_RU
dc.type	Articles in international journals and collections	ru_RU