KFU. Card publication. Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I)

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BOND LENGTHS AND ATOMIC RADII IN COMPOUNDS EX3 (E = N, P, AS, SB; X = F, CL, BR, I)

Form of presentation

Articles in international journals and collections

Year of publication

2022

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Authors, employees of KFU

Khalitov Karim Faritovich, author

Bibliographic description in the original language

Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) / K. F. Khalitov and F. G. Khalitov // Russian Journal of Physical Chemistry A, 2022, Vol. 96, No. 11, pp. 2425–2431

Annotation

Abstract—Correlations between bond lengths d and the first ionization potentials of atoms and molecules are established on the basis of experimental data. Functional dependences are obtained for the series of compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) when � or E are substituted. The difference between dependences with varied E or � are explained by the differing effects on electron pairs of ion E3−. A way of estimating the values of ion radii RE for the elements N, P, As, and Sb is proposed. Interdependences of the values of radii of ions, their dipole moments, and refractions are discussed. The effect substituents X have on the values of radii RE is shown. The values of radii RE(3−) are evaluated for spherically symmetric ions. Linear dependences of radii RE(3−) and ionization potentials of the corresponding ions E3− and atoms of inert gases on their effective charges are established.

Keywords

bond length, ionization potential, compounds EX3 (E = N, P, As, Sb), radii of elements N, P, As, Sb, dipole moments

The name of the journal

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=272093&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Khalitov Karim Faritovich	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) / K. F. Khalitov and F. G. Khalitov // Russian Journal of Physical Chemistry A, 2022, Vol. 96, No. 11, pp. 2425–2431	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=272093&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A	ru_RU
dc.description.abstract	Abstract—Correlations between bond lengths d and the first ionization potentials of atoms and molecules are established on the basis of experimental data. Functional dependences are obtained for the series of compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) when � or E are substituted. The difference between dependences with varied E or � are explained by the differing effects on electron pairs of ion E3−. A way of estimating the values of ion radii RE for the elements N, P, As, and Sb is proposed. Interdependences of the values of radii of ions, their dipole moments, and refractions are discussed. The effect substituents X have on the values of radii RE is shown. The values of radii RE(3−) are evaluated for spherically symmetric ions. Linear dependences of radii RE(3−) and ionization potentials of the corresponding ions E3− and atoms of inert gases on their effective charges are established.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	bond length	ru_RU
dc.subject	ionization potential	ru_RU
dc.subject	compounds EX3 (E = N	ru_RU
dc.subject	P	ru_RU
dc.subject	As	ru_RU
dc.subject	Sb)	ru_RU
dc.subject	radii of elements N	ru_RU
dc.subject	P	ru_RU
dc.subject	As	ru_RU
dc.subject	Sb	ru_RU
dc.subject	dipole moments	ru_RU
dc.title	Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I)	ru_RU
dc.type	Articles in international journals and collections	ru_RU