Form of presentation | Articles in international journals and collections |
Year of publication | 2020 |
Язык | английский |
|
Shulyatev Aleksey Aleksandrovich, author
|
Bibliographic description in the original language |
Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212. |
Annotation |
The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway. |
Keywords |
Diels-Alder reaction, kinetics, molecular complex, solid state |
The name of the journal |
International Journal of Chemical Kinetics
|
URL |
https://onlinelibrary.wiley.com/doi/epdf/10.1002/kin.21434?src=getftr |
Please use this ID to quote from or refer to the card |
https://repository.kpfu.ru/eng/?p_id=271796&p_lang=2 |
Full metadata record ![](https://shelly.kpfu.ru/pdf/picture/arrow_black_right.gif) |
Field DC |
Value |
Language |
dc.contributor.author |
Shulyatev Aleksey Aleksandrovich |
ru_RU |
dc.date.accessioned |
2020-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2020-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2020 |
ru_RU |
dc.identifier.citation |
Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. – 2021. – V.53. – P.207-212. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/eng/?p_id=271796&p_lang=2 |
ru_RU |
dc.description.abstract |
International Journal of Chemical Kinetics |
ru_RU |
dc.description.abstract |
The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracene-tetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
Diels-Alder reaction |
ru_RU |
dc.subject |
kinetics |
ru_RU |
dc.subject |
molecular complex |
ru_RU |
dc.subject |
solid state |
ru_RU |
dc.title |
Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway |
ru_RU |
dc.type |
Articles in international journals and collections |
ru_RU |
|