KFU. Card publication. Nickel on Oxidatively Modified Carbon as a Promising Cost-Efficient Catalyst for Reduction of P-Nitrophenol.

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FEDERAL UNIVERSITY

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NICKEL ON OXIDATIVELY MODIFIED CARBON AS A PROMISING COST-EFFICIENT CATALYST FOR REDUCTION OF P-NITROPHENOL.

Form of presentation

Articles in international journals and collections

Year of publication

2022

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Authors, employees of KFU

Brusko Vasiliy Valerevich, author

Galyaltdinov Shamil Fazlurovich, author

Dimiev Ayrat Maratovich, author

Prytkova Anna Vadimovna, author

Other authors

Kirsanova Mariya Aleksandrovna, author

Authors, postgraduates KFU

Prytkova Anna Vadimovna, postgraduate kfu

Bibliographic description in the original language

Galyaltdinov, S.; Svalova, A.; Brusko, V.; Kirsanova, M.; Dimiev, A.M. Nickel on Oxidatively Modified Carbon as a Promising Cost-Efficient Catalyst for Reduction of P-Nitrophenol. Molecules. - 2022, Vol. 27, P. 5637.

Annotation

The reduction of p-nitrophenol to p-aminophenol has become a benchmark reaction for testing the efficiency of new catalytic systems. In this study, we use oxidatively modified carbon (OMC) as a structural support to develop a new cost-efficient nickel-based catalytic system. The newly developed material comprises single nickel ions, chemically bound to the oxygen functional groups on the OMC surface. The highly oxidized character of OMC ensures the high lateral density of nickel ions on its surface at relatively low nickel content. We demonstrate excellent catalytic properties of the new material by using it as a stationary phase in a prototype of a continuous flow reactor: the reagent fed into the reactor is p-nitrophenol, and the product, exiting the reactor, is the fully converted p-aminophenol. The catalytic properties of the new catalyst are associated with its specific morphology, and with high lateral density of active sites on the surface. The reaction can be considered as an example of single-atom catalysis. The resulting material can be used as an inexpensive but efficient catalyst for industrial wastewater treatment. The study opens the doors for the synthesis of a new series of catalytic systems comprising transition metal atoms on the OMC structural support.

Keywords

oxidatively modified carbon, single-atom catalysis, p-nitrophenol reduction, nickel, UV-spectroscopy

The name of the journal

Molecules (Basel, Switzerland)

URL

https://doi.org/10.3390/molecules27175637

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=270468&p_lang=2

Resource files

File name	Size (MB)	Format
F_molecules_27_05637__2_.pdf	6,53	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Brusko Vasiliy Valerevich	ru_RU
dc.contributor.author	Galyaltdinov Shamil Fazlurovich	ru_RU
dc.contributor.author	Dimiev Ayrat Maratovich	ru_RU
dc.contributor.author	Prytkova Anna Vadimovna	ru_RU
dc.contributor.author	Kirsanova Mariya Aleksandrovna	ru_RU
dc.contributor.author	Prytkova Anna Vadimovna	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Galyaltdinov, S.; Svalova, A.; Brusko, V.; Kirsanova, M.; Dimiev, A.M. Nickel on Oxidatively Modified Carbon as a Promising Cost-Efficient Catalyst for Reduction of P-Nitrophenol. Molecules. - 2022, Vol. 27, P. 5637.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=270468&p_lang=2	ru_RU
dc.description.abstract	Molecules (Basel, Switzerland)	ru_RU
dc.description.abstract	The reduction of p-nitrophenol to p-aminophenol has become a benchmark reaction for testing the efficiency of new catalytic systems. In this study, we use oxidatively modified carbon (OMC) as a structural support to develop a new cost-efficient nickel-based catalytic system. The newly developed material comprises single nickel ions, chemically bound to the oxygen functional groups on the OMC surface. The highly oxidized character of OMC ensures the high lateral density of nickel ions on its surface at relatively low nickel content. We demonstrate excellent catalytic properties of the new material by using it as a stationary phase in a prototype of a continuous flow reactor: the reagent fed into the reactor is p-nitrophenol, and the product, exiting the reactor, is the fully converted p-aminophenol. The catalytic properties of the new catalyst are associated with its specific morphology, and with high lateral density of active sites on the surface. The reaction can be considered as an example of single-atom catalysis. The resulting material can be used as an inexpensive but efficient catalyst for industrial wastewater treatment. The study opens the doors for the synthesis of a new series of catalytic systems comprising transition metal atoms on the OMC structural support.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	oxidatively modified carbon	ru_RU
dc.subject	single-atom catalysis	ru_RU
dc.subject	p-nitrophenol reduction	ru_RU
dc.subject	nickel	ru_RU
dc.subject	UV-spectroscopy	ru_RU
dc.title	Nickel on Oxidatively Modified Carbon as a Promising Cost-Efficient Catalyst for Reduction of P-Nitrophenol.	ru_RU
dc.type	Articles in international journals and collections	ru_RU