KFU. Card publication. Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on selectivity of Ni-catalysed ethylene oligomerization

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INFLUENCE OF N- AND P-SUBSTITUENTS IN N-ARYL-PHOSPHINOGLYCINE LIGANDS ON SELECTIVITY OF NI-CATALYSED ETHYLENE OLIGOMERIZATION

Form of presentation

Articles in international journals and collections

Year of publication

2022

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Authors, employees of KFU

Bekmukhamedov Giyaz Eduardovich, author

Kagilev Aleksey Aleksandrovich, author

Kantyukov Artyom Olegovich, author

Khayarov Khasan Rafaelevich, author

Yakhvarov Dmitriy Grigorevich, author

Other authors

Gafurov Zufar Nafigullovich, author

Zueva Ekaterina Mikhaylovna, author

Kagileva Alina A., author

Sakhapov Ilyas Faridovich, author

Soficheva Olga Sergeevna, author

Bibliographic description in the original language

Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on selectivity of Ni-catalysed ethylene oligomerization / A.A. Kagileva, A.A. Kagilev, A.O. Kantyukov, Z.N. Gafurov, I.F. Sakhapov, G.E. Bekmukhamedov, K.R. Khayarov, E.M. Zueva, O.S. Soficheva, D.G. Yakhvarov // New J. Chem., 2022.

Annotation

Synthesised N-(phenyl)-, N-(pyrazin-2-yl)-, N-(pyridine-3-yl)-, N-(2,5-dimethoxycarbonylphenyl)-, N-(2-methoxycarbonylphenyl)- and newly obtained the so far unknown N-(2-carboxylphenyl)-, N-(pyridine-4-yl)-α-diphenylphosphinoglycines, as well as N-(pyrazin-2-yl)- and N-(2-methoxycarbonylphenyl)-α-mesityl(phenyl)phosphinoglycines were tested as ligands in nickel-catalysed homogeneous ethylene oligomerization. The resulting catalytic systems showed diverse selectivity. Quantum-chemical calculations were performed to rationalize the influence of substituents at nitrogen and phosphorus atoms in N-aryl-phosphinoglycines (L) on the molecular weight distribution of α-olefin products. It was revealed that the difference in catalytic performance of L/Ni systems is mainly due to the steric effects influencing the relative thermodynamic stability of various conformations of the catalyst as well as the thermodynamic and kinetic parameters of various competing catalytic transformations.

Keywords

phosphinoglycine, nickel complex, ethylene oligomerization

The name of the journal

NEW JOURNAL OF CHEMISTRY

URL

https://doi.org/10.1039/D2NJ02578G

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=269368&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Bekmukhamedov Giyaz Eduardovich	ru_RU
dc.contributor.author	Kagilev Aleksey Aleksandrovich	ru_RU
dc.contributor.author	Kantyukov Artyom Olegovich	ru_RU
dc.contributor.author	Khayarov Khasan Rafaelevich	ru_RU
dc.contributor.author	Yakhvarov Dmitriy Grigorevich	ru_RU
dc.contributor.author	Gafurov Zufar Nafigullovich	ru_RU
dc.contributor.author	Zueva Ekaterina Mikhaylovna	ru_RU
dc.contributor.author	Kagileva Alina A.	ru_RU
dc.contributor.author	Sakhapov Ilyas Faridovich	ru_RU
dc.contributor.author	Soficheva Olga Sergeevna	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on selectivity of Ni-catalysed ethylene oligomerization / A.A. Kagileva, A.A. Kagilev, A.O. Kantyukov, Z.N. Gafurov, I.F. Sakhapov, G.E. Bekmukhamedov, K.R. Khayarov, E.M. Zueva, O.S. Soficheva, D.G. Yakhvarov // New J. Chem., 2022.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=269368&p_lang=2	ru_RU
dc.description.abstract	NEW JOURNAL OF CHEMISTRY	ru_RU
dc.description.abstract	Synthesised N-(phenyl)-, N-(pyrazin-2-yl)-, N-(pyridine-3-yl)-, N-(2,5-dimethoxycarbonylphenyl)-, N-(2-methoxycarbonylphenyl)- and newly obtained the so far unknown N-(2-carboxylphenyl)-, N-(pyridine-4-yl)-α-diphenylphosphinoglycines, as well as N-(pyrazin-2-yl)- and N-(2-methoxycarbonylphenyl)-α-mesityl(phenyl)phosphinoglycines were tested as ligands in nickel-catalysed homogeneous ethylene oligomerization. The resulting catalytic systems showed diverse selectivity. Quantum-chemical calculations were performed to rationalize the influence of substituents at nitrogen and phosphorus atoms in N-aryl-phosphinoglycines (L) on the molecular weight distribution of α-olefin products. It was revealed that the difference in catalytic performance of L/Ni systems is mainly due to the steric effects influencing the relative thermodynamic stability of various conformations of the catalyst as well as the thermodynamic and kinetic parameters of various competing catalytic transformations.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	phosphinoglycine	ru_RU
dc.subject	nickel complex	ru_RU
dc.subject	ethylene oligomerization	ru_RU
dc.title	Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on selectivity of Ni-catalysed ethylene oligomerization	ru_RU
dc.type	Articles in international journals and collections	ru_RU