Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
FROM THE STEREOCHEMISTRY OF A MOLECULE TO THE STEREOCHEMISTRY OF A CRYSTAL: CHIRAL CRYSTALLIZATION OF ENDO-ISOMERS COMPARED WITH CENTROSYMMETRIC CRYSTALLIZATION OF EXO-ISOMERS OF THIIRANE AND OXIRANE DERIVATIVES OF PHENYL- SUBSTITUTED SEVEN-MEMBERED ACETAL
Form of presentationArticles in international journals and collections
Year of publication2021
Языканглийский
  • Pavelev Roman Sergeevich, author
  • Bibliographic description in the original language Gerasimova D. P., Pavelyev R. S., Lodochnikova O. A., FROM THE STEREOCHEMISTRY OF A MOLECULE TO THE STEREOCHEMISTRY OF A CRYSTAL: CHIRAL CRYSTALLIZATION OF ENDO-ISOMERS COMPARED WITH CENTROSYMMETRIC CRYSTALLIZATION OF EXO-ISOMERS OF THIIRANE AND OXIRANE DERIVATIVES OF PHENYL- SUBSTITUTED SEVEN-MEMBERED ACETAL//JOURNAL OF STRUCTURAL CHEMISTRY. - 2021. - Vol.62, Is.11. - P.1694-1702.
    Annotation The chiral type of crystallization of endo-isomers of 4-phenyl-3,5,8-trioxabicyclo[5.1.0]octane and 4-phenyl-3,5-dioxa-8-thiabicyclo[5.1.0]octane and the formation of racemic crystals by molecules corresponding exo-isomers are established. The relationship between the structural organization of molecules and the stereochemical type of intermolecular interactions and the formation of different types of crystals is analyzed.
    Keywords chiral crystallization, achiral compounds, intermolecular interactions
    The name of the journal Journal of Structural Chemistry
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=263349&p_lang=2

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