KFU. Card publication. Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2− with formation of finely dispersed Pd0

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METHYL VIOLOGEN AND TETRAVIOLOGEN CALIX[4]RESORCINOL AS MEDIATORS OF THE ELECTROCHEMICAL REDUCTION OF [PDCL4]2− WITH FORMATION OF FINELY DISPERSED PD0

Form of presentation

Articles in international journals and collections

Year of publication

2014

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Authors, employees of KFU

Ziganshina Albina Yulduzovna, author

Bibliographic description in the original language

V. V. Yanilkin, G. R. Nasybullina, E. D. Sultanova, A. Yu. Ziganshina, and A. I. Konovalov, Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2– with formation of finely dispersed Pd0 // Russ. Chem. Bull. – 2014. – 63. – 6. – 1409—1415.

Annotation

Methyl viologen and tetraviologen calix[4]resorcinol with decyl substituents in the resorcinol cycles (MVCA-C10 8+) are mediators of the electrochemical reduction of complex dianion [PdCl4]2− facilitating its reduction on the glassy carbon electrode at 0.5–0.6 V. The reduction product of Pd2+ salt is finely dispersed metallic palladium, and its structure and some properties are determined by the mediator nature. When using methyl viologen, palladium is deposited on the electrode and dispersed as flakes in a solution, whereas in the case of MVCA-C10 8+ palladium is completely deposited on the electrode as nanoparticles together with calixresorcinol.

Keywords

viologen calix[4]resorcinol, palladium tetrachloride, mediator, electrochemical reduction, palladium particles

The name of the journal

Russian Chemical Bulletin

URL

https://link.springer.com/article/10.1007/s11172-014-0611-x#citeas

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=262936&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziganshina Albina Yulduzovna	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	V. V. Yanilkin, G. R. Nasybullina, E. D. Sultanova, A. Yu. Ziganshina, and A. I. Konovalov, Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2– with formation of finely dispersed Pd0 // Russ. Chem. Bull. – 2014. – 63. – 6. – 1409—1415.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=262936&p_lang=2	ru_RU
dc.description.abstract	Russian Chemical Bulletin	ru_RU
dc.description.abstract	Methyl viologen and tetraviologen calix[4]resorcinol with decyl substituents in the resorcinol cycles (MVCA-C10 8+) are mediators of the electrochemical reduction of complex dianion [PdCl4]2− facilitating its reduction on the glassy carbon electrode at 0.5–0.6 V. The reduction product of Pd2+ salt is finely dispersed metallic palladium, and its structure and some properties are determined by the mediator nature. When using methyl viologen, palladium is deposited on the electrode and dispersed as flakes in a solution, whereas in the case of MVCA-C10 8+ palladium is completely deposited on the electrode as nanoparticles together with calixresorcinol.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	viologen calix[4]resorcinol	ru_RU
dc.subject	palladium tetrachloride	ru_RU
dc.subject	mediator	ru_RU
dc.subject	electrochemical reduction	ru_RU
dc.subject	palladium particles	ru_RU
dc.title	Methyl viologen and tetraviologen calix[4]resorcinol as mediators of the electrochemical reduction of [PdCl4]2− with formation of finely dispersed Pd0	ru_RU
dc.type	Articles in international journals and collections	ru_RU