KFU. Card publication. Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol

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ELECTROCHEMICALLY CONTROLLED BINDING OF BIS-P,P-CHELATE PLATINUM(II) DICATION TO 3,7-DI(2-PYRIDYL)-1,5-DIPHENYL-1,5-DIAZA-3,7-DIPHOSPHACYCLOOCTANE COMPLEX AND FERROCYANIDE ION WITH TETRAVIOLOGEN CALIX[4]RESORCINOL

Form of presentation

Articles in international journals and collections

Year of publication

2015

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Authors, employees of KFU

Ziganshina Albina Yulduzovna, author

Bibliographic description in the original language

G. R. Nasybullina, V. V. Yanilkin, R. R. Fazleeva, A. Yu. Ziganshina, I. D. Strelnik, Yu. S. Spiridonova, A. S. Balueva, E. I. Musina, A. A. Karasik. / Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol // Russ. Chem. Bull. – 2015. – 64. – 291—305.

Annotation

Two new types of systems with an electrochemically controlled binding of electron-accepting particles with tetra(methyl viologen) calix[4]resorcinol MVCA-C5 8+ were developed. Control is carried out by the reversible reduction of viologen units. In one of the systems, an equimolar amount of the dication of bis-P,P-chelate platinum(II)—3,7-di(2-pyridyl)-1,5diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex ([PtL1 2]2+) is bound by the reduced form MVCA-C5 0 and is not bound to the octacation MVCA-C5 8+ and tetra(radical cation) MVCA-C5 4+?. In another ternary system MVCA-C5 8+—[PtL1 2]2+—[Fe(CN)6]3–, the reversible switching occurs from the original unbound state to the state with selective binding of equimolar amounts of [Fe(CN)6]4– or [PtL1 2]2+ by calixresorcinol. Supramolecular complexes form insoluble associates in both systems.

Keywords

calix[4]resorcinol, methyl viologen, platinum(II) complex, binding, electrochemical control

The name of the journal

Russian Chemical Bulletin

URL

https://link.springer.com/article/10.1007/s11172-015-0859-9#citeas

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=262930&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziganshina Albina Yulduzovna	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	G. R. Nasybullina, V. V. Yanilkin, R. R. Fazleeva, A. Yu. Ziganshina, I. D. Strelnik, Yu. S. Spiridonova, A. S. Balueva, E. I. Musina, A. A. Karasik. / Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol // Russ. Chem. Bull. – 2015. – 64. – 291—305.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=262930&p_lang=2	ru_RU
dc.description.abstract	Russian Chemical Bulletin	ru_RU
dc.description.abstract	Two new types of systems with an electrochemically controlled binding of electron-accepting particles with tetra(methyl viologen) calix[4]resorcinol MVCA-C5 8+ were developed. Control is carried out by the reversible reduction of viologen units. In one of the systems, an equimolar amount of the dication of bis-P,P-chelate platinum(II)—3,7-di(2-pyridyl)-1,5diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex ([PtL1 2]2+) is bound by the reduced form MVCA-C5 0 and is not bound to the octacation MVCA-C5 8+ and tetra(radical cation) MVCA-C5 4+?. In another ternary system MVCA-C5 8+—[PtL1 2]2+—[Fe(CN)6]3–, the reversible switching occurs from the original unbound state to the state with selective binding of equimolar amounts of [Fe(CN)6]4– or [PtL1 2]2+ by calixresorcinol. Supramolecular complexes form insoluble associates in both systems.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	calix[4]resorcinol	ru_RU
dc.subject	methyl viologen	ru_RU
dc.subject	platinum(II) complex	ru_RU
dc.subject	binding	ru_RU
dc.subject	electrochemical control	ru_RU
dc.title	Electrochemically controlled binding of bis-P,P-chelate platinum(II) dication to 3,7-di(2-pyridyl)-1,5-diphenyl-1,5-diaza-3,7-diphosphacyclooctane complex and ferrocyanide ion with tetraviologen calix[4]resorcinol	ru_RU
dc.type	Articles in international journals and collections	ru_RU