Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
ELECTROCHEMICAL SYNTHESIS OF NANOCOMPOSITE OF PALLADIUM NANOPARTICLES WITH POLYMER VIOLOGEN-CONTAINING NANOCAPSULES
Form of presentationArticles in international journals and collections
Year of publication2016
Языканглийский
  • Ziganshina Albina Yulduzovna, author
  • Bibliographic description in the original language V. V. Yanilkin, N. V. Nastapova, E. D. Sultanova, G. R. Nasretdinova, R. K. Mukhitova, A. Yu. Ziganshina, I. R. Nizameev, M. K. Kadirov Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsules // Russ. Chem. Bull. – 2016. – 65. – 125-132.
    Annotation An efficient mediated electrosynthesis of the spherical (85 nm) nanocomposite material Pd@p(MVCA8+-co-St) was carried out in an aqueous medium. Ultrasmall palladium nanoparticles (3—8 nm) are stabilized in nanocapsules of water-soluble nanoparticles of the copolymer p(MVCA8+-co-St) consisting of tetraviologen calix[4]resorcinol (MVCA8+) with styrene (St). The role of the mediator is played by viologen units of a polymer nanoparticle at potentials of the MV2+/MV∙+ redox couple. The high catalytic activity of the nanocomposite material in the reduction of nitrophenol with sodium borohydride is shown.
    Keywords nanoparticle, palladium, viologen, resorcinarene
    The name of the journal Russian Chemical Bulletin
    URL https://link.springer.com/article/10.1007%2Fs11172-016-1274-6#citeas
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=262912&p_lang=2

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