KFU. Card publication. Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications

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FEDERAL UNIVERSITY

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METALLOSURFACTANTS: FROM FUNDAMENTALS TO CATALYTIC AND BIOMEDICAL APPLICATIONS

Form of presentation

International monographs

Year of publication

2022

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Authors, employees of KFU

Ziganshina Albina Yulduzovna, author

Bibliographic description in the original language

Zhiltsova, E.P. Supramolecular Metal-Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self-Assembling Behavior and Practical Applications / E. P. Zhiltsova, M. R. Ibatullina, R. R. Kashapov, N. E. Kashapova, A. Y. Ziganshina, L. Y. Zakharova, O. G. Sinyashin // Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications, Book Editor(s):Surinder Mehta,Ravneet Kaur, 2022. – Chapter 12. – P. 223-248.

Annotation

The chapter focuses on metal-bearing nanocontainers of different types. First, typical metallosurfactants are discussed, with their synthesis, self-assembling behavior, solubilization properties, and morphological characteristics emphasized. In this section, different metals and ligands are considered, and their influence on aggregation thresholds and structural characteristics is analyzed. These micellar nanocontainers are of particular importance from the viewpoint of biomedical application due to their own antimicrobial properties and therapeutic effects. In addition, the complexation of metallosurfactants with biomolecules is mentioned. Second, development of a conceptually new trend for amphiphilic and supra-amphiphilic system based on metallosurfactants and macrocycles is considered. The design of nanoscale superstructure construction from flexible surfactant molecules and solid macrocycles is being actively developed, but the creation of metallosurfactant/macrocycle compositions has only just begun and limited with few studies. Supramolecular aggregates based on metalloamphiphile–macrocycle complexes have several advantages, such as the simplicity of preparing and further modification with stimulus-sensitive and targeting ligands, and their selective biological activity. Third, catalytically active silver- and palladium-loaded nanocomposites based on amphiphilic resorcinarene macrocycles were developed. For these hybrid supramolecular and polymer nanocontainers, the influence of the morphology and the structure of the organic shell on the stability and catalytic activity are shown.

Keywords

nanocontainers, resorcinarene

URL

https://onlinelibrary.wiley.com/doi/10.1002/9783527831289.ch12

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=262814&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziganshina Albina Yulduzovna	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Zhiltsova, E.P. Supramolecular Metal-Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self-Assembling Behavior and Practical Applications / E. P. Zhiltsova, M. R. Ibatullina, R. R. Kashapov, N. E. Kashapova, A. Y. Ziganshina, L. Y. Zakharova, O. G. Sinyashin // Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications, Book Editor(s):Surinder Mehta,Ravneet Kaur, 2022. – Chapter 12. – P. 223-248.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=262814&p_lang=2	ru_RU
dc.description.abstract	The chapter focuses on metal-bearing nanocontainers of different types. First, typical metallosurfactants are discussed, with their synthesis, self-assembling behavior, solubilization properties, and morphological characteristics emphasized. In this section, different metals and ligands are considered, and their influence on aggregation thresholds and structural characteristics is analyzed. These micellar nanocontainers are of particular importance from the viewpoint of biomedical application due to their own antimicrobial properties and therapeutic effects. In addition, the complexation of metallosurfactants with biomolecules is mentioned. Second, development of a conceptually new trend for amphiphilic and supra-amphiphilic system based on metallosurfactants and macrocycles is considered. The design of nanoscale superstructure construction from flexible surfactant molecules and solid macrocycles is being actively developed, but the creation of metallosurfactant/macrocycle compositions has only just begun and limited with few studies. Supramolecular aggregates based on metalloamphiphile–macrocycle complexes have several advantages, such as the simplicity of preparing and further modification with stimulus-sensitive and targeting ligands, and their selective biological activity. Third, catalytically active silver- and palladium-loaded nanocomposites based on amphiphilic resorcinarene macrocycles were developed. For these hybrid supramolecular and polymer nanocontainers, the influence of the morphology and the structure of the organic shell on the stability and catalytic activity are shown.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	nanocontainers	ru_RU
dc.subject	resorcinarene	ru_RU
dc.title	Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications	ru_RU
dc.type	International monographs	ru_RU