Form of presentation | International monographs |
Year of publication | 2022 |
Язык | английский |
|
Ziganshina Albina Yulduzovna, author
|
Bibliographic description in the original language |
Zhiltsova, E.P. Supramolecular Metal-Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self-Assembling Behavior and Practical Applications / E. P. Zhiltsova, M. R. Ibatullina, R. R. Kashapov, N. E. Kashapova, A. Y. Ziganshina, L. Y. Zakharova, O. G. Sinyashin // Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications, Book Editor(s):Surinder Mehta,Ravneet Kaur, 2022. – Chapter 12. – P. 223-248. |
Annotation |
The chapter focuses on metal-bearing nanocontainers of different types. First, typical metallosurfactants are discussed, with their synthesis, self-assembling behavior, solubilization properties, and morphological characteristics emphasized. In this section, different metals and ligands are considered, and their influence on aggregation thresholds and structural characteristics is analyzed. These micellar nanocontainers are of particular importance from the viewpoint of biomedical application due to their own antimicrobial properties and therapeutic effects. In addition, the complexation of metallosurfactants with biomolecules is mentioned. Second, development of a conceptually new trend for amphiphilic and supra-amphiphilic system based on metallosurfactants and macrocycles is considered. The design of nanoscale superstructure construction from flexible surfactant molecules and solid macrocycles is being actively developed, but the creation of metallosurfactant/macrocycle compositions has only just begun and limited with few studies. Supramolecular aggregates based on metalloamphiphile–macrocycle complexes have several advantages, such as the simplicity of preparing and further modification with stimulus-sensitive and targeting ligands, and their selective biological activity. Third, catalytically active silver- and palladium-loaded nanocomposites based on amphiphilic resorcinarene macrocycles were developed. For these hybrid supramolecular and polymer nanocontainers, the influence of the morphology and the structure of the organic shell on the stability and catalytic activity are shown. |
Keywords |
nanocontainers, resorcinarene |
URL |
https://onlinelibrary.wiley.com/doi/10.1002/9783527831289.ch12 |
Please use this ID to quote from or refer to the card |
https://repository.kpfu.ru/eng/?p_id=262814&p_lang=2 |
Full metadata record ![](https://shelly.kpfu.ru/pdf/picture/arrow_black_right.gif) |
Field DC |
Value |
Language |
dc.contributor.author |
Ziganshina Albina Yulduzovna |
ru_RU |
dc.date.accessioned |
2022-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2022-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2022 |
ru_RU |
dc.identifier.citation |
Zhiltsova, E.P. Supramolecular Metal-Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self-Assembling Behavior and Practical Applications / E. P. Zhiltsova, M. R. Ibatullina, R. R. Kashapov, N. E. Kashapova, A. Y. Ziganshina, L. Y. Zakharova, O. G. Sinyashin // Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications, Book Editor(s):Surinder Mehta,Ravneet Kaur, 2022. – Chapter 12. – P. 223-248. |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/eng/?p_id=262814&p_lang=2 |
ru_RU |
dc.description.abstract |
The chapter focuses on metal-bearing nanocontainers of different types. First, typical metallosurfactants are discussed, with their synthesis, self-assembling behavior, solubilization properties, and morphological characteristics emphasized. In this section, different metals and ligands are considered, and their influence on aggregation thresholds and structural characteristics is analyzed. These micellar nanocontainers are of particular importance from the viewpoint of biomedical application due to their own antimicrobial properties and therapeutic effects. In addition, the complexation of metallosurfactants with biomolecules is mentioned. Second, development of a conceptually new trend for amphiphilic and supra-amphiphilic system based on metallosurfactants and macrocycles is considered. The design of nanoscale superstructure construction from flexible surfactant molecules and solid macrocycles is being actively developed, but the creation of metallosurfactant/macrocycle compositions has only just begun and limited with few studies. Supramolecular aggregates based on metalloamphiphile–macrocycle complexes have several advantages, such as the simplicity of preparing and further modification with stimulus-sensitive and targeting ligands, and their selective biological activity. Third, catalytically active silver- and palladium-loaded nanocomposites based on amphiphilic resorcinarene macrocycles were developed. For these hybrid supramolecular and polymer nanocontainers, the influence of the morphology and the structure of the organic shell on the stability and catalytic activity are shown. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
nanocontainers |
ru_RU |
dc.subject |
resorcinarene |
ru_RU |
dc.title |
Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications |
ru_RU |
dc.type |
International monographs |
ru_RU |
|