KFU. Card publication. Temperature sensitivity of Nd3+, Yb3+: YF3 ratiometric luminescent thermometers at different Yb3+ concentration

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FEDERAL UNIVERSITY

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TEMPERATURE SENSITIVITY OF ND3+, YB3+: YF3 RATIOMETRIC LUMINESCENT THERMOMETERS AT DIFFERENT YB3+ CONCENTRATION

Form of presentation

Articles in international journals and collections

Year of publication

2021

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Authors, employees of KFU

Lukinova Elena , author

Pudovkin Maksim Sergeevich, author

Authors, students KFU

Ginkel Anna Konstantinovna, author

Bibliographic description in the original language

Pudovkin, M. S., Ginkel, A. K., & Lukinova, E. V. (2021). Temperature sensitivity of Nd3+, Yb3+: YF3 ratiometric luminescent thermometers at different Yb3+ concentration. Optical Materials, 119, 111328.

Annotation

Nd3+ (0.5 mol.%), Yb3+ (1.0, 2.0, 3.0, 4.0, and 8.0 mol.%):YF3 phosphors were synthesized using a coprecipitation method with subsequent hydrothermal treatment and annealing in vacuum. The Nd3+, Yb3+:YF3 phosphors are orthorhombic phase nano-crystals. Luminescence intensity ratio (LIR) of Nd3+ (4F3/2 – 4I9/2, ~866 nm) and Yb3+ (2F5/2 – 2F7/2, ~980 nm) emissions was chosen as temperature-dependent parameter. The energy exchange between 4F3/2 (Nd3+) and 2F5/2 (Yb3+) is phonon-assisted which explains the temperature dependence of LIR. There are Nd3+ to Yb3+ energy transfer (ET), Yb3+ to Nd3+ back energy transfer (BET) and energy diffusion (ED) between Yb3+ ions. The probability of BET decreases with the increase of Yb3+ concentration which leads to LIR dependence on Yb3+ concentration. The maximum absolute temperature sensitivity (Sa) was achieved for Nd3+ (0.5%), Yb3+ (1.0%):YF3 (Sa = 0.0018 K􀀀 1 at 148 K). The studied samples demonstrate high stability after 8 cooling-heating cycles. The Nd3+ (0.5%), Yb3+ (1.0%):YF3 phosphors are very promising for temperature sensing.

Keywords

Luminescent thermometry Nd3+ Yb3+:YF3 Down-conversion Optical temperature sensors LIR

The name of the journal

Optical Materials

URL

https://www.sciencedirect.com/science/article/pii/S0925346721005292

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=255067&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Lukinova Elena	ru_RU
dc.contributor.author	Pudovkin Maksim Sergeevich	ru_RU
dc.contributor.author	Ginkel Anna Konstantinovna	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Pudovkin, M. S., Ginkel, A. K., & Lukinova, E. V. (2021). Temperature sensitivity of Nd3+, Yb3+: YF3 ratiometric luminescent thermometers at different Yb3+ concentration. Optical Materials, 119, 111328.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=255067&p_lang=2	ru_RU
dc.description.abstract	Optical Materials	ru_RU
dc.description.abstract	Nd3+ (0.5 mol.%), Yb3+ (1.0, 2.0, 3.0, 4.0, and 8.0 mol.%):YF3 phosphors were synthesized using a coprecipitation method with subsequent hydrothermal treatment and annealing in vacuum. The Nd3+, Yb3+:YF3 phosphors are orthorhombic phase nano-crystals. Luminescence intensity ratio (LIR) of Nd3+ (4F3/2 – 4I9/2, ~866 nm) and Yb3+ (2F5/2 – 2F7/2, ~980 nm) emissions was chosen as temperature-dependent parameter. The energy exchange between 4F3/2 (Nd3+) and 2F5/2 (Yb3+) is phonon-assisted which explains the temperature dependence of LIR. There are Nd3+ to Yb3+ energy transfer (ET), Yb3+ to Nd3+ back energy transfer (BET) and energy diffusion (ED) between Yb3+ ions. The probability of BET decreases with the increase of Yb3+ concentration which leads to LIR dependence on Yb3+ concentration. The maximum absolute temperature sensitivity (Sa) was achieved for Nd3+ (0.5%), Yb3+ (1.0%):YF3 (Sa = 0.0018 K􀀀 1 at 148 K). The studied samples demonstrate high stability after 8 cooling-heating cycles. The Nd3+ (0.5%), Yb3+ (1.0%):YF3 phosphors are very promising for temperature sensing.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Temperature sensitivity of Nd3+, Yb3+: YF3 ratiometric luminescent thermometers at different Yb3+ concentration	ru_RU
dc.type	Articles in international journals and collections	ru_RU