KFU. Card publication. Structural and hydrogen absorption/desorption properties of Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy

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FEDERAL UNIVERSITY

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STRUCTURAL AND HYDROGEN ABSORPTION/DESORPTION PROPERTIES OF ZR2(CO0.5FE0.2NI0.2V0.1) INTERMETALLIC ALLOY

Form of presentation

Articles in international journals and collections

Year of publication

2021

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Authors, employees of KFU

Vagizov Farit Gabdulkhakovich, author

Yusupov Roman Valerevich, author

Other authors

Arabi H. , author

Ghorbani S. R., author

Komeili M. , author

Pourarian F. , author

Bibliographic description in the original language

Komeili M. Structural and hydrogen absorption/desorption properties of Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy/ M. Komeili, H.Arabi, R.V.Yusupov, S.R.Ghorbani, F.G.Vagizov, F.Pourarian //International Journal of Hydrogen Energy. - 2021. - Vol., Is.. - .

Annotation

The Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy was prepared by arc melting method and its physical properties and hydrogen storage performance were investigated. XRD analysis by Rietveld refinement and Mössbauer spectroscopy measurements revealed a multiphase crystal structure, in which the dominant phases are C16 Laves phase. The hydrogen-induced cracks, chemical composition, and elements distribution were analyzed by SEM and EDX mapping. The optimum conditions for the activation process, hydrogen absorption kinetics, cyclic durability performance, and disproportionation behavior were discussed. Zr2(Co0.5Fe0.2Ni0.2V0.1) alloy has a high absorption kinetic rate, with an activation energy of 10.11 kJ/mol, high hydrogen capacity (2.1 wt%) at room temperature, and good anti-disproportionation behavior (hydrogen pressure up to 8 bar and temperature below 783K). The hydrogen capacity decreased in the first three cycles (~25%) and then remained almost stable, which is likely caused by the high stability of hydride. The studied hydride has interesting features that can be considered for practical applications.

Keywords

Activation parameters, Anti-disproportionation, Hydrogen absorption, 57Fe Mössbauer, Hydrogen kinetics, Zr2(Co0.5Fe0.2Ni0.2V0.1) alloy

The name of the journal

International Journal of Hydrogen Energy

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85103967915&doi=10.1016%2fj.ijhydene.2021.03.045&partnerID=40&md5=ad1f3b84efbe4399d64019eccdf46905

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=252605&p_lang=2

Resource files

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F_Structural_and_hydrogen_absorption_desorption_properties_of_Zr2_Co0.5Fe0.2Ni0.2V0.1__intermetallic_alloy_.pdf	3,35	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Vagizov Farit Gabdulkhakovich	ru_RU
dc.contributor.author	Yusupov Roman Valerevich	ru_RU
dc.contributor.author	Arabi H.	ru_RU
dc.contributor.author	Ghorbani S. R.	ru_RU
dc.contributor.author	Komeili M.	ru_RU
dc.contributor.author	Pourarian F.	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Komeili M. Structural and hydrogen absorption/desorption properties of Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy/ M. Komeili, H.Arabi, R.V.Yusupov, S.R.Ghorbani, F.G.Vagizov, F.Pourarian //International Journal of Hydrogen Energy. - 2021. - Vol., Is.. - .	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=252605&p_lang=2	ru_RU
dc.description.abstract	International Journal of Hydrogen Energy	ru_RU
dc.description.abstract	The Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy was prepared by arc melting method and its physical properties and hydrogen storage performance were investigated. XRD analysis by Rietveld refinement and Mössbauer spectroscopy measurements revealed a multiphase crystal structure, in which the dominant phases are C16 Laves phase. The hydrogen-induced cracks, chemical composition, and elements distribution were analyzed by SEM and EDX mapping. The optimum conditions for the activation process, hydrogen absorption kinetics, cyclic durability performance, and disproportionation behavior were discussed. Zr2(Co0.5Fe0.2Ni0.2V0.1) alloy has a high absorption kinetic rate, with an activation energy of 10.11 kJ/mol, high hydrogen capacity (2.1 wt%) at room temperature, and good anti-disproportionation behavior (hydrogen pressure up to 8 bar and temperature below 783K). The hydrogen capacity decreased in the first three cycles (~25%) and then remained almost stable, which is likely caused by the high stability of hydride. The studied hydride has interesting features that can be considered for practical applications.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Activation parameters	ru_RU
dc.subject	Anti-disproportionation	ru_RU
dc.subject	Hydrogen absorption	ru_RU
dc.subject	57Fe Mössbauer	ru_RU
dc.subject	Hydrogen kinetics	ru_RU
dc.subject	Zr2(Co0.5Fe0.2Ni0.2V0.1) alloy	ru_RU
dc.title	Structural and hydrogen absorption/desorption properties of Zr2(Co0.5Fe0.2Ni0.2V0.1) intermetallic alloy	ru_RU
dc.type	Articles in international journals and collections	ru_RU