KFU. Card publication. Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio

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NANOASSOCIATES OF AMPHIPHILICCARBOXY-CALIXRESORCINARENE AND CETYLPYRIDINUIM CHLORIDE: THE SEARCH OF OPTIMAL MACROCYCLE/SURFACTANT MOLAR RATIO

Form of presentation

Articles in international journals and collections

Year of publication

2018

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Authors, employees of KFU

Ermakova Alina Marselovna, author

Konovalov Aleksandr Ivanovich, author

Morozova Yuliya Ernestovna, author

Shalaeva Yana Viktorovna, author

Other authors

Kadirov Marsil Kakhirovich, author

Nizameev Irek Rashatovich, author

Syakaev Viktor Vasilevich, author

Bibliographic description in the original language

Morozova J. E., Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio. / Morozova J. E., Syakaev V. V., Shalaeva Y. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Konovalov A. I. // Colloids Surf., A. – 2018. – V. 553. – P. 569-577. DOI: 10.1016/j.colsurfa.2018.05.077

Annotation

Here we present the supramolecular surfactant-macrocycle system which properties are independent on system composition in the wide range of components concentrations. The study of the interaction of octacarboxy-tetra(p-phenylene-oxy-pentyl)calixresorcinarene (C5R) and cetylpyridinuim chloride (CPC) in mixed aqueous solutions were performed by dynamic light scattering and electrophoretic methods, 1H and FT-PGSE NMR methods, absorption and ﬂuorescence spectroscopy, and TEM. The variation of CPC/C5R molar ratio from 30/1 to 10/1 leads to the formation of nanoassociates with similar composition, size, surface potential value, and improved (in compare with CPC) solubilizing properties. The preparation of mixed supramolecular systems which properties are independent on system composition in the wide range of components concentrations is an elegant example of the producing of colloidal materials with the required morphology and properties.

Keywords

Calix[4]resorcinarene, Cetylpyridinuim chloride, Supramolecular system, FT-PGSE NMR, Solubilization

The name of the journal

Colloids and Surfaces A: Physicochemical and Engineering Aspects

URL

https://www.sciencedirect.com/science/article/pii/S0927775718304539?via%3Dihub

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=241478&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ermakova Alina Marselovna	ru_RU
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Morozova Yuliya Ernestovna	ru_RU
dc.contributor.author	Shalaeva Yana Viktorovna	ru_RU
dc.contributor.author	Kadirov Marsil Kakhirovich	ru_RU
dc.contributor.author	Nizameev Irek Rashatovich	ru_RU
dc.contributor.author	Syakaev Viktor Vasilevich	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	Morozova J. E., Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio. / Morozova J. E., Syakaev V. V., Shalaeva Y. V., Ermakova A. M., Nizameev I. R., Kadirov M. K., Konovalov A. I. // Colloids Surf., A. – 2018. – V. 553. – P. 569-577. DOI: 10.1016/j.colsurfa.2018.05.077	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=241478&p_lang=2	ru_RU
dc.description.abstract	Colloids and Surfaces A: Physicochemical and Engineering Aspects	ru_RU
dc.description.abstract	Here we present the supramolecular surfactant-macrocycle system which properties are independent on system composition in the wide range of components concentrations. The study of the interaction of octacarboxy-tetra(p-phenylene-oxy-pentyl)calixresorcinarene (C5R) and cetylpyridinuim chloride (CPC) in mixed aqueous solutions were performed by dynamic light scattering and electrophoretic methods, 1H and FT-PGSE NMR methods, absorption and ﬂuorescence spectroscopy, and TEM. The variation of CPC/C5R molar ratio from 30/1 to 10/1 leads to the formation of nanoassociates with similar composition, size, surface potential value, and improved (in compare with CPC) solubilizing properties. The preparation of mixed supramolecular systems which properties are independent on system composition in the wide range of components concentrations is an elegant example of the producing of colloidal materials with the required morphology and properties.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calix[4]resorcinarene	ru_RU
dc.subject	Cetylpyridinuim chloride	ru_RU
dc.subject	Supramolecular system	ru_RU
dc.subject	FT-PGSE NMR	ru_RU
dc.subject	Solubilization	ru_RU
dc.title	Nanoassociates of amphiphiliccarboxy-calixresorcinarene and cetylpyridinuim chloride: the search of optimal macrocycle/surfactant molar ratio	ru_RU
dc.type	Articles in international journals and collections	ru_RU