KFU. Card publication. One-step synthesis of gold colloids using amidoamino-calix[4]resorcinarenes as reducing and stabilizing agents. Investigation of naproxen binding

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ONE-STEP SYNTHESIS OF GOLD COLLOIDS USING AMIDOAMINO-CALIX[4]RESORCINARENES AS REDUCING AND STABILIZING AGENTS. INVESTIGATION OF NAPROXEN BINDING

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Ermakova Alina Marselovna, author

Konovalov Aleksandr Ivanovich, author

Morozova Yuliya Ernestovna, author

Shalaeva Yana Viktorovna, author

Other authors

Kadirov Marsil Kakhirovich, author

Kazakova Ella Khatibovna, author

Nizameev Irek Rashatovich, author

Bibliographic description in the original language

Ya. V. Shalaeva, One-step synthesis of gold colloids using amidoamino-calix[4]resorcinarenes as reducing and stabilizing agents. Investigation of naproxen binding /Ya. V. Shalaeva, Ju. E. Morozova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, E. Kh. Kazakova, A. I. Konovalov // Colloids and Surfaces A. – 2017. V. 527. – P. 1 – 10. DOI: 10.1016/j.colsurfa.2017.04.079

Annotation

Amido(dimethylamino) calix[4]resorcinarenes with diﬀerent substituents on the lower rim (-CH3 (�1), −C5H11 (C5), −C11H23 (C11)) both as reducing and stabilizing agent in an aqueous solution were used for the fabrication of stable gold colloids. Gold colloids are characterized by spectrophotometry, FTIR − spectroscopy, transmission electron microscopy, dynamic light scattering. It is found that increase of the macrocycle's concentration towards HAuCl4 concentration during the synthesis leads to the decrease in the size of formed particles. It is shown that the size of gold nanoparticles (AuNPs) decreases with the increase of the hydrophobicity of the substituents on the macrocycles lower rim (C1@Au − 4–14 nm, C5@Au - 10–11 nm, C11@Au − 7–8 nm). The monolayer packing of the macrocycle molecules on the surface of the metal particle for C1@Au and bilayer − for C5@Au and C11@Au, providing both the stabilization of AuNPs and their solubility in water, are proposed. Temperature and pH variation during the synthesis showed that the optimal synthesis conditions for all kinds of particles C1@Au, C5@Au, C11@Au are spontaneous installed during the synthesis pH (for C1@Au − pH 8.10, C5@Au − pH 8.56, C11@Au − pH 8.63) and the synthesis temperature of the 25 ?C. High binding fraction of drug substrate naproxen on the surface of AuNPs modiﬁed by C5 and C11 macrocyclic aggregates due to the ordering of the macrocycles on the particle surface and enhancing their receptor ability towards naproxen is deﬁned by ﬂuorescence method.

Keywords

Calixresorcinarenes, Gold colloids, Nanoparticles, Reducing and stabilizing agent

The name of the journal

Colloids and Surfaces A: Physicochemical and Engineering Aspects

URL

https://www.sciencedirect.com/science/article/pii/S092777571730420X?via%3Dihub

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=241474&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ermakova Alina Marselovna	ru_RU
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Morozova Yuliya Ernestovna	ru_RU
dc.contributor.author	Shalaeva Yana Viktorovna	ru_RU
dc.contributor.author	Kadirov Marsil Kakhirovich	ru_RU
dc.contributor.author	Kazakova Ella Khatibovna	ru_RU
dc.contributor.author	Nizameev Irek Rashatovich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Ya. V. Shalaeva, One-step synthesis of gold colloids using amidoamino-calix[4]resorcinarenes as reducing and stabilizing agents. Investigation of naproxen binding /Ya. V. Shalaeva, Ju. E. Morozova, A. M. Ermakova, I. R. Nizameev, M. K. Kadirov, E. Kh. Kazakova, A. I. Konovalov // Colloids and Surfaces A. – 2017. V. 527. – P. 1 – 10. DOI: 10.1016/j.colsurfa.2017.04.079	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=241474&p_lang=2	ru_RU
dc.description.abstract	Colloids and Surfaces A: Physicochemical and Engineering Aspects	ru_RU
dc.description.abstract	Amido(dimethylamino) calix[4]resorcinarenes with diﬀerent substituents on the lower rim (-CH3 (�1), −C5H11 (C5), −C11H23 (C11)) both as reducing and stabilizing agent in an aqueous solution were used for the fabrication of stable gold colloids. Gold colloids are characterized by spectrophotometry, FTIR − spectroscopy, transmission electron microscopy, dynamic light scattering. It is found that increase of the macrocycle's concentration towards HAuCl4 concentration during the synthesis leads to the decrease in the size of formed particles. It is shown that the size of gold nanoparticles (AuNPs) decreases with the increase of the hydrophobicity of the substituents on the macrocycles lower rim (C1@Au − 4–14 nm, C5@Au - 10–11 nm, C11@Au − 7–8 nm). The monolayer packing of the macrocycle molecules on the surface of the metal particle for C1@Au and bilayer − for C5@Au and C11@Au, providing both the stabilization of AuNPs and their solubility in water, are proposed. Temperature and pH variation during the synthesis showed that the optimal synthesis conditions for all kinds of particles C1@Au, C5@Au, C11@Au are spontaneous installed during the synthesis pH (for C1@Au − pH 8.10, C5@Au − pH 8.56, C11@Au − pH 8.63) and the synthesis temperature of the 25 ?C. High binding fraction of drug substrate naproxen on the surface of AuNPs modiﬁed by C5 and C11 macrocyclic aggregates due to the ordering of the macrocycles on the particle surface and enhancing their receptor ability towards naproxen is deﬁned by ﬂuorescence method.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calixresorcinarenes	ru_RU
dc.subject	Gold colloids	ru_RU
dc.subject	Nanoparticles	ru_RU
dc.subject	Reducing and stabilizing agent	ru_RU
dc.title	One-step synthesis of gold colloids using amidoamino-calix[4]resorcinarenes as reducing and stabilizing agents. Investigation of naproxen binding	ru_RU
dc.type	Articles in international journals and collections	ru_RU