KFU. Card publication. Electrochemical properties of N-Substituted α-diphenylphosphinoglycines

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

ELECTROCHEMICAL PROPERTIES OF N-SUBSTITUTED α-DIPHENYLPHOSPHINOGLYCINES

Form of presentation

Articles in international journals and collections

Year of publication

2020

Язык

английский

Authors, employees of KFU

Yakhvarov Dmitriy Grigorevich, author

Bibliographic description in the original language

Electrochemical properties of N-Substituted α-diphenylphosphinoglycines / O.S. Soficheva, Yu.A. Kislitsyn, A.A. Nesterova, A.B. Dobrynin, D.G. Yakhvarov // Russ. J. Electrochem. – 2020. – V. 56(5). – P. 431-436.

Annotation

methoxybenzyl) diphenylphosphinoglycine (1), N-(pyrazin-2-yl) diphenylphosphinoglycine (2), N-(1-adamantyl) diphenylphosphinoglycine (3), and N-(2,5-dimethoxycarbonylphenyl) diphenylphosphinoglycine (4) obtained in the three-component condensation of iphenylphosphine, glyoxylic acid hydrate, and the corresponding amine were studied by cyclic voltammetry on a glassy carbon electrode. The structure of compound 4 was confirmed by X-ray diffraction analysis. Compounds 1–4 exhibited electrochemical activity in the anodic region of potentials due to the presence of an oxidizable diphenylphosphine fragment in the molecule. Compound 4 can also be electrochemically reduced at the cathodic potentials of the working electrode due to the ester groups in the aromatic fragment.

Keywords

α-phosphino-α-amino acids, α-diphenylphosphinoglycines, reduction, oxidation, X-ray diffraction analysis, cyclic voltammetry, lectrochemical properties

The name of the journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=235483&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Yakhvarov Dmitriy Grigorevich	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Electrochemical properties of N-Substituted α-diphenylphosphinoglycines / O.S. Soficheva, Yu.A. Kislitsyn, A.A. Nesterova, A.B. Dobrynin, D.G. Yakhvarov // Russ. J. Electrochem. – 2020. – V. 56(5). – P. 431-436.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=235483&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF ELECTROCHEMISTRY	ru_RU
dc.description.abstract	methoxybenzyl) diphenylphosphinoglycine (1), N-(pyrazin-2-yl) diphenylphosphinoglycine (2), N-(1-adamantyl) diphenylphosphinoglycine (3), and N-(2,5-dimethoxycarbonylphenyl) diphenylphosphinoglycine (4) obtained in the three-component condensation of iphenylphosphine, glyoxylic acid hydrate, and the corresponding amine were studied by cyclic voltammetry on a glassy carbon electrode. The structure of compound 4 was confirmed by X-ray diffraction analysis. Compounds 1–4 exhibited electrochemical activity in the anodic region of potentials due to the presence of an oxidizable diphenylphosphine fragment in the molecule. Compound 4 can also be electrochemically reduced at the cathodic potentials of the working electrode due to the ester groups in the aromatic fragment.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	α-phosphino-α-amino acids	ru_RU
dc.subject	α-diphenylphosphinoglycines	ru_RU
dc.subject	reduction	ru_RU
dc.subject	oxidation	ru_RU
dc.subject	X-ray diffraction analysis	ru_RU
dc.subject	cyclic voltammetry	ru_RU
dc.subject	lectrochemical properties	ru_RU
dc.title	Electrochemical properties of N-Substituted α-diphenylphosphinoglycines	ru_RU
dc.type	Articles in international journals and collections	ru_RU