KFU. Card publication. The selective electrochemical sensing of naringin using electropolymerized ellagic acid film

KAZAN
FEDERAL UNIVERSITY

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THE SELECTIVE ELECTROCHEMICAL SENSING OF NARINGIN USING ELECTROPOLYMERIZED ELLAGIC ACID FILM

Form of presentation

Articles in international journals and collections

Year of publication

2020

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Authors, employees of KFU

Budnikov German Konstantinovich, author

Guss Ekaterina Valerevna, author

Ziyatdinova Guzel Kamilevna, author

Yakupova Elvira Nailevna, author

Authors, postgraduates KFU

Yakupova Elvira Nailevna, postgraduate kfu

Bibliographic description in the original language

Ziyatdinova, G. The selective electrochemical sensing of naringin using electropolymerized ellagic acid film / G. Ziyatdinova, E. Yakupova, E. Guss, H. Budnikov //Journal of the Electrochemical Society. - 2020. - V. 167. - � 10. - Art. � 107502. - 10 p.

Annotation

Electrochemical sensor on the basis of glassy carbon electrode (GCE) covered with multi-walled carbon nanotubes and electropolymerized ellagic acid (polyEA/MWNT/GCE) has been developed for the naringin determination. Polymeric film has been obtained by potentiodynamic electrolysis. The working conditions of polymeric coverage formation (scans number, supporting electrolyte pH, monomer concentration and electrolysis parameters) providing the best naringin response have been found. Ellagic acid (EA) electropolymerization has to be performed from 10 μM monomer by sevenfold cycling of potential in the range of 0.0?1.0 V at the scan rate of 100 mV s−1 in phosphate buffer (PB) pH 7.0. Scanning electron microscopy (SEM) confirms successful modification of the sensor surface with evenly distributed 30?50 nm spherical particles providing 9.6-fold increase of the electrode effective surface area vs GCE. Naringin electrooxidation parameters on polyEA/MWNT/GCE have been found. Sensor acting under conditions of differential pulse voltammetry in PB pH 6.5 provides linear dynamic ranges of 0.050?1.0 and 1.0?100 μM with the detection and quantification limits of 14 and 47 nM, respectively. The selectivity of sensor towards naringin in the presence of inorganic ions, saccharides, hesperidin, ascorbic and phenolic acids is proved. The sensor developed has been successfully tested on grapefruit juices.

Keywords

Voltammetry, chemically modified electrodes, electropolymerization, phenolic acids, naringin, food analysis

The name of the journal

Journal of the Electrochemical Society

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85086513673&doi=10.1149%2f1945-7111%2fab9280&partnerID=40&md5=bd99b5a46b9516c496848888fa692aac

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=234346&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Budnikov German Konstantinovich	ru_RU
dc.contributor.author	Guss Ekaterina Valerevna	ru_RU
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Yakupova Elvira Nailevna	ru_RU
dc.contributor.author	Yakupova Elvira Nailevna	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Ziyatdinova, G. The selective electrochemical sensing of naringin using electropolymerized ellagic acid film / G. Ziyatdinova, E. Yakupova, E. Guss, H. Budnikov //Journal of the Electrochemical Society. - 2020. - V. 167. - � 10. - Art. � 107502. - 10 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=234346&p_lang=2	ru_RU
dc.description.abstract	Journal of the Electrochemical Society	ru_RU
dc.description.abstract	Electrochemical sensor on the basis of glassy carbon electrode (GCE) covered with multi-walled carbon nanotubes and electropolymerized ellagic acid (polyEA/MWNT/GCE) has been developed for the naringin determination. Polymeric film has been obtained by potentiodynamic electrolysis. The working conditions of polymeric coverage formation (scans number, supporting electrolyte pH, monomer concentration and electrolysis parameters) providing the best naringin response have been found. Ellagic acid (EA) electropolymerization has to be performed from 10 μM monomer by sevenfold cycling of potential in the range of 0.0?1.0 V at the scan rate of 100 mV s−1 in phosphate buffer (PB) pH 7.0. Scanning electron microscopy (SEM) confirms successful modification of the sensor surface with evenly distributed 30?50 nm spherical particles providing 9.6-fold increase of the electrode effective surface area vs GCE. Naringin electrooxidation parameters on polyEA/MWNT/GCE have been found. Sensor acting under conditions of differential pulse voltammetry in PB pH 6.5 provides linear dynamic ranges of 0.050?1.0 and 1.0?100 μM with the detection and quantification limits of 14 and 47 nM, respectively. The selectivity of sensor towards naringin in the presence of inorganic ions, saccharides, hesperidin, ascorbic and phenolic acids is proved. The sensor developed has been successfully tested on grapefruit juices.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Voltammetry	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	electropolymerization	ru_RU
dc.subject	phenolic acids	ru_RU
dc.subject	naringin	ru_RU
dc.subject	food analysis	ru_RU
dc.title	The selective electrochemical sensing of naringin using electropolymerized ellagic acid film	ru_RU
dc.type	Articles in international journals and collections	ru_RU