KFU. Card publication. Ni-based complexes in selective ethylene oligomerization processes

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

NI-BASED COMPLEXES IN SELECTIVE ETHYLENE OLIGOMERIZATION PROCESSES

Form of presentation

Articles in international journals and collections

Year of publication

2020

Язык

английский

Authors, employees of KFU

Bekmukhamedov Giyaz Eduardovich, author

Kuchkaev Aydar Maratovich, author

Sukhov Aleksandr Vyacheslavovich, author

Yakhvarov Dmitriy Grigorevich, author

Authors, postgraduates KFU

Kuchkaev Aydar Maratovich, postgraduate kfu

Bibliographic description in the original language

Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Yakhvarov, D.G. Ni-based complexes in selective ethylene oligomerization processes. Catalysts. 2020, 10, 498. DOI:10.3390/catal10050498

Annotation

Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.

Keywords

homogeneous catalysis, ethylene oligomerization, nickel complexes, catalytic activity, selectivity, imine ligands, organophosphorus ligands, carbene ligands

The name of the journal

Catalysts

URL

https://ex.kpfu.ru/owa/redir.aspx?C=whk6cRwW4Khg2tRdNy_Xk1rcC-Eum4kTVAWPLS6En9MoMF7-bwjYCA..&URL=https%3a%2f%2fwww.mdpi.com%2f2073-4344%2f10%2f5%2f498

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=233305&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Bekmukhamedov Giyaz Eduardovich	ru_RU
dc.contributor.author	Kuchkaev Aydar Maratovich	ru_RU
dc.contributor.author	Sukhov Aleksandr Vyacheslavovich	ru_RU
dc.contributor.author	Yakhvarov Dmitriy Grigorevich	ru_RU
dc.contributor.author	Kuchkaev Aydar Maratovich	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Bekmukhamedov, G.E.; Sukhov, A.V.; Kuchkaev, A.M.; Yakhvarov, D.G. Ni-based complexes in selective ethylene oligomerization processes. Catalysts. 2020, 10, 498. DOI:10.3390/catal10050498	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=233305&p_lang=2	ru_RU
dc.description.abstract	Catalysts	ru_RU
dc.description.abstract	Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	homogeneous catalysis	ru_RU
dc.subject	ethylene oligomerization	ru_RU
dc.subject	nickel complexes	ru_RU
dc.subject	catalytic activity	ru_RU
dc.subject	selectivity	ru_RU
dc.subject	imine ligands	ru_RU
dc.subject	organophosphorus ligands	ru_RU
dc.subject	carbene ligands	ru_RU
dc.title	Ni-based complexes in selective ethylene oligomerization processes	ru_RU
dc.type	Articles in international journals and collections	ru_RU