KFU. Card publication. Volumetric behaviour of six ionic liquids from T = (278 to 398) K and up to 120 MPa

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VOLUMETRIC BEHAVIOUR OF SIX IONIC LIQUIDS FROM T = (278 TO 398) K AND UP TO 120 MPA

Form of presentation

Articles in international journals and collections

Year of publication

2016

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Authors, employees of KFU

Bolotov Aleksandr Vladimirovich, author

Bibliographic description in the original language

Gacino F.M, Regueira T, Bolotov A.V, Volumetric behaviour of six ionic liquids from T = (278 to 398) K and up to 120 MPa//Journal of Chemical Thermodynamics. - 2016. - Vol.93, Is.. - P.24-33.

Annotation

In this paper the volumetric behaviour of the ionic liquids 1-butyl-1-methylpyrrolidinium tetracyanoborate, 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate, 1,3-dimethylimidazolium dimethylphosphate, 1-ethyl-3-methylimidazolium hexylsulfate, and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate is reported. Density was measured over the temperature range (278.15 to 398.15) K up to 120 MPa by means of a high pressure densimeter based on the vibrating tube principle. Experimental values were correlated as a function of temperature and pressure by means of the Tammann–Tait equation obtaining standard deviations lower than 3 × 10−4 g ? cm−3. From this correlation, isothermal compressibility and isobaric thermal expansivity are obtained by differentiation. Furthermore, two group contribution methods proposed by Gardas and Coutinho and by Jacquemin et al. are applied to these fluids to analyse their prediction abilities to determine densities, as well as an equation proposed by Kiselev et al. to obtain isothermal compressibility at 0.1 MPa.

Keywords

DensityPressureIonic liquidIsothermal compressibilityThermal expansivity

The name of the journal

Journal of Chemical Thermodynamics

URL

http://www.scopus.com/inward/record.url?eid=2-s2.0-84943386701&partnerID=40&md5=9bb7614203633d37b1b4e41073091e9d

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=229277&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Bolotov Aleksandr Vladimirovich	ru_RU
dc.date.accessioned	2016-01-01T00:00:00Z	ru_RU
dc.date.available	2016-01-01T00:00:00Z	ru_RU
dc.date.issued	2016	ru_RU
dc.identifier.citation	Gacino F.M, Regueira T, Bolotov A.V, Volumetric behaviour of six ionic liquids from T = (278 to 398) K and up to 120 MPa//Journal of Chemical Thermodynamics. - 2016. - Vol.93, Is.. - P.24-33.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=229277&p_lang=2	ru_RU
dc.description.abstract	Journal of Chemical Thermodynamics	ru_RU
dc.description.abstract	In this paper the volumetric behaviour of the ionic liquids 1-butyl-1-methylpyrrolidinium tetracyanoborate, 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate, 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate, 1,3-dimethylimidazolium dimethylphosphate, 1-ethyl-3-methylimidazolium hexylsulfate, and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate is reported. Density was measured over the temperature range (278.15 to 398.15) K up to 120 MPa by means of a high pressure densimeter based on the vibrating tube principle. Experimental values were correlated as a function of temperature and pressure by means of the Tammann–Tait equation obtaining standard deviations lower than 3 × 10−4 g ? cm−3. From this correlation, isothermal compressibility and isobaric thermal expansivity are obtained by differentiation. Furthermore, two group contribution methods proposed by Gardas and Coutinho and by Jacquemin et al. are applied to these fluids to analyse their prediction abilities to determine densities, as well as an equation proposed by Kiselev et al. to obtain isothermal compressibility at 0.1 MPa.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Volumetric behaviour of six ionic liquids from T = (278 to 398) K and up to 120 MPa	ru_RU
dc.type	Articles in international journals and collections	ru_RU