KFU. Card publication. Silica nanoparticles with dual visible-NIR luminescence affected by silica confinement of Tb(III) and Yb(III) complexes for cellular imaging application

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SILICA NANOPARTICLES WITH DUAL VISIBLE-NIR LUMINESCENCE AFFECTED BY SILICA CONFINEMENT OF TB(III) AND YB(III) COMPLEXES FOR CELLULAR IMAGING APPLICATION

Form of presentation

Articles in international journals and collections

Year of publication

2019

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Authors, employees of KFU

Daminova Amina Galeevna, author

Bibliographic description in the original language

S. Fedorenko, D. Gilmanova, A. Mukhametshina, I. Nizameev, K. Kholin, B. Akhmadeev, A. Voloshina, A. Sapunova, S. Kuznetsova, A. Daminova, S. Katsyuba, R. Zairov, A. Mustafina / Silica nanoparticles with dual visible-NIR luminescence affected by silica confinement of Tb(III) and Yb(III) complexes for cellular imaging application // Journal of materials science. 2019. Vol. 54(12). P. 9140-9154.

Annotation

The work introduces silica confinement of Tb(III) and Yb(III) complexes with psulfonatothiacalix[4]arene (TCAS) arisen from their doping into silica nanoparticles (51–60 nm) as the reason for efficient dual green–NIR luminescence. pH-regulated water solubility of the lanthanide complexes is highlighted as prerequisite for the balance between efficient doping of the complexes into silica nanoparticles and their size/shape university. The impact of Tb(III) ? Yb(III) energy transfer on the NIR and visible luminescence of the nanoparticles was revealed from photophysical studies of the nanoparticles doped with different couples of lanthanide complexes (Tb–Gd, Tb–Yb, Yb–Gd) at various molar ratios. The optimal balance between green and NIR luminescence is achieved for the silica nanoparticles doped with Tb–Yb complexes at 2:1 (Tb:Yb) ratio due to both Tb(III) ? Yb(III) energy transfer and specific distribution of Tb(III) and Yb(III) complexes within silica nanoparticles. The dual luminescent nanoparticles exhibit efficient cellular uptake behavior after amino-decoration of their surface, which is confirmed by confocal microscopy images of the cells incubated by the heterometallic nanoparticles.

Keywords

Silica nanoparticles,Tb?Yb complexes, luminescence

The name of the journal

Journal of Materials Science

URL

https://link.springer.com/article/10.1007/s10853-019-03532-6

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=216170&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Daminova Amina Galeevna	ru_RU
dc.date.accessioned	2019-01-01T00:00:00Z	ru_RU
dc.date.available	2019-01-01T00:00:00Z	ru_RU
dc.date.issued	2019	ru_RU
dc.identifier.citation	S. Fedorenko, D. Gilmanova, A. Mukhametshina, I. Nizameev, K. Kholin, B. Akhmadeev, A. Voloshina, A. Sapunova, S. Kuznetsova, A. Daminova, S. Katsyuba, R. Zairov, A. Mustafina / Silica nanoparticles with dual visible-NIR luminescence affected by silica confinement of Tb(III) and Yb(III) complexes for cellular imaging application // Journal of materials science. 2019. Vol. 54(12). P. 9140-9154.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=216170&p_lang=2	ru_RU
dc.description.abstract	Journal of Materials Science	ru_RU
dc.description.abstract	The work introduces silica confinement of Tb(III) and Yb(III) complexes with psulfonatothiacalix[4]arene (TCAS) arisen from their doping into silica nanoparticles (51–60 nm) as the reason for efficient dual green–NIR luminescence. pH-regulated water solubility of the lanthanide complexes is highlighted as prerequisite for the balance between efficient doping of the complexes into silica nanoparticles and their size/shape university. The impact of Tb(III) ? Yb(III) energy transfer on the NIR and visible luminescence of the nanoparticles was revealed from photophysical studies of the nanoparticles doped with different couples of lanthanide complexes (Tb–Gd, Tb–Yb, Yb–Gd) at various molar ratios. The optimal balance between green and NIR luminescence is achieved for the silica nanoparticles doped with Tb–Yb complexes at 2:1 (Tb:Yb) ratio due to both Tb(III) ? Yb(III) energy transfer and specific distribution of Tb(III) and Yb(III) complexes within silica nanoparticles. The dual luminescent nanoparticles exhibit efficient cellular uptake behavior after amino-decoration of their surface, which is confirmed by confocal microscopy images of the cells incubated by the heterometallic nanoparticles.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Silica nanoparticles	ru_RU
dc.subject	Tb?Yb complexes	ru_RU
dc.subject	luminescence	ru_RU
dc.title	Silica nanoparticles with dual visible-NIR luminescence affected by silica confinement of Tb(III) and Yb(III) complexes for cellular imaging application	ru_RU
dc.type	Articles in international journals and collections	ru_RU