KFU. Card publication. α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization

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FEDERAL UNIVERSITY

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α-DIPHENYLPHOSPHINO-N-(PYRAZIN-2-YL)GLYCINE AS A LIGAND IN NI-CATALYZED ETHYLENE OLIGOMERIZATION

Form of presentation

Articles in international journals and collections

Year of publication

2019

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Authors, employees of KFU

Bekmukhamedov Giyaz Eduardovich, author

Yakhvarov Dmitriy Grigorevich, author

Other authors

Heinicke Joachim W., author

Dobrynin Aleksey Borisovich, author

Sinyashin Oleg Geroldovich, author

Soficheva Olga Sergeevna, author

Bibliographic description in the original language

Soficheva O. S. α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization / O. S. Soficheva, G. E. Bekmukhamedov, A. B. Dobrynin, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov // Mendeleev Communications. - 2019. - V. 29, I. 5. - P. 575-577.

Annotation

a-Diphenylphosphino-N-(pyrazin-2-yl)glycine was synthesized by the three-component condensation of diphenylphosphine, glyoxylic acid hydrate, and 2-aminopyrazine and its structure was confirmed by X-ray diffraction. It reacted with [Ni(COD)2] (COD is cycloocta-1,5-diene) to give complexes that were tested as catalysts for selective dimerization/oligomerization of ethylene to but-1-ene (main product) and C6–C14 a-olefins, respectively.

Keywords

nickel, Diphenylphosphinoglycine, ligand, oligomerization

The name of the journal

MENDELEEV COMMUNICATIONS

URL

https://www.sciencedirect.com/science/article/pii/S0959943619302433

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=215713&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Bekmukhamedov Giyaz Eduardovich	ru_RU
dc.contributor.author	Yakhvarov Dmitriy Grigorevich	ru_RU
dc.contributor.author	Heinicke Joachim W.	ru_RU
dc.contributor.author	Dobrynin Aleksey Borisovich	ru_RU
dc.contributor.author	Sinyashin Oleg Geroldovich	ru_RU
dc.contributor.author	Soficheva Olga Sergeevna	ru_RU
dc.date.accessioned	2019-01-01T00:00:00Z	ru_RU
dc.date.available	2019-01-01T00:00:00Z	ru_RU
dc.date.issued	2019	ru_RU
dc.identifier.citation	Soficheva O. S. α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization / O. S. Soficheva, G. E. Bekmukhamedov, A. B. Dobrynin, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov // Mendeleev Communications. - 2019. - V. 29, I. 5. - P. 575-577.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=215713&p_lang=2	ru_RU
dc.description.abstract	MENDELEEV COMMUNICATIONS	ru_RU
dc.description.abstract	a-Diphenylphosphino-N-(pyrazin-2-yl)glycine was synthesized by the three-component condensation of diphenylphosphine, glyoxylic acid hydrate, and 2-aminopyrazine and its structure was confirmed by X-ray diffraction. It reacted with [Ni(COD)2] (COD is cycloocta-1,5-diene) to give complexes that were tested as catalysts for selective dimerization/oligomerization of ethylene to but-1-ene (main product) and C6–C14 a-olefins, respectively.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	nickel	ru_RU
dc.subject	Diphenylphosphinoglycine	ru_RU
dc.subject	ligand	ru_RU
dc.subject	oligomerization	ru_RU
dc.title	α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization	ru_RU
dc.type	Articles in international journals and collections	ru_RU