KFU. Card publication. Polyurethane ionomers based on amino ethers of ortho-phosphoric acid

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FEDERAL UNIVERSITY

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POLYURETHANE IONOMERS BASED ON AMINO ETHERS OF ORTHO-PHOSPHORIC ACID

Form of presentation

Articles in international journals and collections

Year of publication

2019

Язык

английский

Authors, employees of KFU

Klochkov Vladimir Vasilevich, author

Other authors

Davletbaev Ruslan Sagitovich, author

Davletbaeva Ilsiya Mullayanovna, author

Sazonov Oleg , author

Fazlyev Azat Ravilevich, author

Bibliographic description in the original language

Polyurethane ionomers based on amino ethers of ortho-phosphoric acid / I.M. Davletbaeva, O.O. Sazonov, A.R. Fazlyev, R.S. Davletbaev, S.V. Efimov, V.V. Klochkov // RSC Advances. – 2019. – V. 9. – P. 18599-18608. – DOI 10.1039/c9ra03636a

Annotation

The etherification of ortho-phosphoric acid with triethanolamine and polyoxypropylene glycol is studied. The reaction process is accompanied by the formation of hyperbranched amino ethers of orthophosphoric acid terminated by hydroxyl groups. A specific feature of the chemical structure of the compounds obtained is the existence of ion pairs in their structure separated in space. The reaction of the etherification of ortho-phosphoric acid with glycols becomes possible through the use of tertiary amines. The amino ethers of ortho-phosphoric acid are investigated as a polyol component for the synthesis of polyurethanes with high adhesion characteristics and strength properties. The experimental results presented allow us to relate polyurethanes obtained on the basis of ortho-phosphoric acid amino ethers to polymers of ionomeric nature.

Keywords

ionomers, polyurethane, coating, FTIR spectrosocpy, NMR spectroscopy

The name of the journal

RSC Advances

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=204494&p_lang=2

Resource files

File name	Size (MB)	Format
F_Polyurethane_ionomers_based_on_amino_ethers_of_orto_phosphoric_acid.pdf	1,32	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Klochkov Vladimir Vasilevich	ru_RU
dc.contributor.author	Davletbaev Ruslan Sagitovich	ru_RU
dc.contributor.author	Davletbaeva Ilsiya Mullayanovna	ru_RU
dc.contributor.author	Sazonov Oleg	ru_RU
dc.contributor.author	Fazlyev Azat Ravilevich	ru_RU
dc.date.accessioned	2019-01-01T00:00:00Z	ru_RU
dc.date.available	2019-01-01T00:00:00Z	ru_RU
dc.date.issued	2019	ru_RU
dc.identifier.citation	Polyurethane ionomers based on amino ethers of ortho-phosphoric acid / I.M. Davletbaeva, O.O. Sazonov, A.R. Fazlyev, R.S. Davletbaev, S.V. Efimov, V.V. Klochkov // RSC Advances. – 2019. – V. 9. – P. 18599-18608. – DOI 10.1039/c9ra03636a	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=204494&p_lang=2	ru_RU
dc.description.abstract	RSC Advances	ru_RU
dc.description.abstract	The etherification of ortho-phosphoric acid with triethanolamine and polyoxypropylene glycol is studied. The reaction process is accompanied by the formation of hyperbranched amino ethers of orthophosphoric acid terminated by hydroxyl groups. A specific feature of the chemical structure of the compounds obtained is the existence of ion pairs in their structure separated in space. The reaction of the etherification of ortho-phosphoric acid with glycols becomes possible through the use of tertiary amines. The amino ethers of ortho-phosphoric acid are investigated as a polyol component for the synthesis of polyurethanes with high adhesion characteristics and strength properties. The experimental results presented allow us to relate polyurethanes obtained on the basis of ortho-phosphoric acid amino ethers to polymers of ionomeric nature.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	ionomers	ru_RU
dc.subject	polyurethane	ru_RU
dc.subject	coating	ru_RU
dc.subject	FTIR spectrosocpy	ru_RU
dc.subject	NMR spectroscopy	ru_RU
dc.title	Polyurethane ionomers based on amino ethers of ortho-phosphoric acid	ru_RU
dc.type	Articles in international journals and collections	ru_RU