KFU. Card publication. On the Long-Range Exciton Transport in Molecular Systems: The Application to H-Aggregated Heterotriangulene Chains

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FEDERAL UNIVERSITY

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ON THE LONG-RANGE EXCITON TRANSPORT IN MOLECULAR SYSTEMS: THE APPLICATION TO H-AGGREGATED HETEROTRIANGULENE CHAINS

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Proshin Yuriy Nikolaevich, author

Saykin Semen Konstantinovich, author

Shakirov Mars Aydarovich, author

Bibliographic description in the original language

Shakirov M., On the Long-Range Exciton Transport in Molecular Systems: The Application to H-Aggregated Heterotriangulene Chains / M. Shakirov, S. K. Saikin, Y. Proshin// J. Phys. Chem. C20171214524994-25002

Annotation

Self-assembled aggregates of pigment molecules are potential building blocks for excitonic circuits that find their application in energy conversion and optical signal processing. Recent experimental studies of one-dimensional heterotriangulene supramolecular aggregates suggested that singlet excitons in these structures can propagate on several micron distances. We explore this possibility theoretically by combining electronic structure calculations with microscopic models for exciton transport. A detailed characterization of the structural disorder and exciton decoherence is provided. We argue that advanced, well-established exciton transport models, used in our study, give about one order of magnitude shorter estimates for the exciton propagation length which suggest that there are other possible explanations of the experimental results.

Keywords

Molecular aggregates, exciton energy transport, heterotriangulene chains

The name of the journal

Journal of Chemical Physics

URL

https://pubs.acs.org/doi/abs/10.1021/acs.jpcc.7b08933

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=202741&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Proshin Yuriy Nikolaevich	ru_RU
dc.contributor.author	Saykin Semen Konstantinovich	ru_RU
dc.contributor.author	Shakirov Mars Aydarovich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Shakirov M., On the Long-Range Exciton Transport in Molecular Systems: The Application to H-Aggregated Heterotriangulene Chains / M. Shakirov, S. K. Saikin, Y. Proshin// J. Phys. Chem. C20171214524994-25002	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=202741&p_lang=2	ru_RU
dc.description.abstract	Journal of Chemical Physics	ru_RU
dc.description.abstract	Self-assembled aggregates of pigment molecules are potential building blocks for excitonic circuits that find their application in energy conversion and optical signal processing. Recent experimental studies of one-dimensional heterotriangulene supramolecular aggregates suggested that singlet excitons in these structures can propagate on several micron distances. We explore this possibility theoretically by combining electronic structure calculations with microscopic models for exciton transport. A detailed characterization of the structural disorder and exciton decoherence is provided. We argue that advanced, well-established exciton transport models, used in our study, give about one order of magnitude shorter estimates for the exciton propagation length which suggest that there are other possible explanations of the experimental results.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Molecular aggregates	ru_RU
dc.subject	exciton energy transport	ru_RU
dc.subject	heterotriangulene chains	ru_RU
dc.title	On the Long-Range Exciton Transport in Molecular Systems: The Application to H-Aggregated Heterotriangulene Chains	ru_RU
dc.type	Articles in international journals and collections	ru_RU