KFU. Card publication. Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid

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FEDERAL UNIVERSITY

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ELECTROCHEMICAL AMINATION OF CHLOROBENZENE IN AQUEOUS-ORGANIC SOLUTIONS OF SULFURIC ACID

Form of presentation

Articles in international journals and collections

Year of publication

2018

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Authors, employees of KFU

Lisicyn Yuriy Anatolevich, author

Sukhov Aleksandr Vyacheslavovich, author

Bibliographic description in the original language

Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.11. - P.886-892.

Annotation

The process of electrochemical amination of chlorobenzene using hydroxylamine and the Ti(IV)/Ti(III) mediator system is studied in aqueous solutions of 6–16 M sulfuric acid containing acetic acid or acetonitrile. The substitution products in these media are isomeric chloroanilines and chlorophenylenediamines, with the exception of 5-chloro-1,3-isomer, phenylenediamines, and aniline. The overall current efficiency of amino compounds corresponding under the experimental conditions to the efficiency by hydroxylamine can reach 71%. Para- and ortho-chloroanilines are obtained in 6 M sulfuric acid and 11.1 M acetic acid with the weight fraction and current efficiency of 97 and 51%, respectively.

Keywords

cathode, Ti(IV)/Ti(III) mediator system, hydroxylamine, amino cation?radical, chlorobenzene, cation?radical aromatic substitution, chloroanilines, chlorophenylenediamines

The name of the journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061324774&doi=10.1134%2fS1023193518130268&partnerID=40&md5=ca34cf8e805662b38d6377d1e194163d

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=197921&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Lisicyn Yuriy Anatolevich	ru_RU
dc.contributor.author	Sukhov Aleksandr Vyacheslavovich	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	Lisitsyn Y.A, Sukhov A.V., Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid//Russian Journal of Electrochemistry. - 2018. - Vol.54, Is.11. - P.886-892.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=197921&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF ELECTROCHEMISTRY	ru_RU
dc.description.abstract	The process of electrochemical amination of chlorobenzene using hydroxylamine and the Ti(IV)/Ti(III) mediator system is studied in aqueous solutions of 6–16 M sulfuric acid containing acetic acid or acetonitrile. The substitution products in these media are isomeric chloroanilines and chlorophenylenediamines, with the exception of 5-chloro-1,3-isomer, phenylenediamines, and aniline. The overall current efficiency of amino compounds corresponding under the experimental conditions to the efficiency by hydroxylamine can reach 71%. Para- and ortho-chloroanilines are obtained in 6 M sulfuric acid and 11.1 M acetic acid with the weight fraction and current efficiency of 97 and 51%, respectively.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	cathode	ru_RU
dc.subject	Ti(IV)/Ti(III) mediator system	ru_RU
dc.subject	hydroxylamine	ru_RU
dc.subject	amino cation?radical	ru_RU
dc.subject	chlorobenzene	ru_RU
dc.subject	cation?radical aromatic substitution	ru_RU
dc.subject	chloroanilines	ru_RU
dc.subject	chlorophenylenediamines	ru_RU
dc.title	Electrochemical Amination of Chlorobenzene in Aqueous-Organic Solutions of Sulfuric Acid	ru_RU
dc.type	Articles in international journals and collections	ru_RU