KFU. Card publication. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)(Article)

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COMPLEX FORMATION OF 1,5-BIS(AMIDOMETHYLSULFONYL)PENTANE WITH COPPER(II) AND IRON(III)(ARTICLE)

Form of presentation

Articles in international journals and collections

Year of publication

2018

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Authors, employees of KFU

Amirov Rustem Rafaelevich, author

Neklyudov Vadim Vyacheslavovich, author

Chmutova Galina Alekseevna, author

Other authors

Shulaeva Marina Mikhaylovna, author

Authors, students KFU

Bagina Yuliya Igorevna, author

Bibliographic description in the original language

Neklyudov, V.V. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III) / V.V. Neklyudov, G.A. Boos, G.A. Chmutova, M.M. Shulaeva, Y.I. Bagina, R.R. Amirov // Russian Journal of General Chemistry. - 2018. - Volume 88, Issue 8. P. 1672-1680.

Annotation

The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.

Keywords

The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10?5 to 1.00 × 10?3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.

The name of the journal

Russian Journal of General Chemistry

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=190369&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Amirov Rustem Rafaelevich	ru_RU
dc.contributor.author	Neklyudov Vadim Vyacheslavovich	ru_RU
dc.contributor.author	Chmutova Galina Alekseevna	ru_RU
dc.contributor.author	Shulaeva Marina Mikhaylovna	ru_RU
dc.contributor.author	Bagina Yuliya Igorevna	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	Neklyudov, V.V. Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III) / V.V. Neklyudov, G.A. Boos, G.A. Chmutova, M.M. Shulaeva, Y.I. Bagina, R.R. Amirov // Russian Journal of General Chemistry. - 2018. - Volume 88, Issue 8. P. 1672-1680.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=190369&p_lang=2	ru_RU
dc.description.abstract	Russian Journal of General Chemistry	ru_RU
dc.description.abstract	The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25?C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	The state of the new antitubercular agent 1	ru_RU
dc.subject	5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry	ru_RU
dc.subject	pH potentiometry (25?C	ru_RU
dc.subject	variable ionic strength)	ru_RU
dc.subject	and mathematical modeling. In the concentration range from 5.00 × 10?5 to 1.00 × 10?3 M in the presence of Bridge 35	ru_RU
dc.subject	the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1	ru_RU
dc.subject	5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.	ru_RU
dc.title	Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)(Article)	ru_RU
dc.type	Articles in international journals and collections	ru_RU