KFU. Card publication. Self-assembly of chiral fluorescent nanoparticles based on water-soluble L-tryptophan derivatives of p-tert-butylthiacalix[4]arene

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SELF-ASSEMBLY OF CHIRAL FLUORESCENT NANOPARTICLES BASED ON WATER-SOLUBLE L-TRYPTOPHAN DERIVATIVES OF P-TERT-BUTYLTHIACALIX[4]ARENE

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Vorobev Vyacheslav Valerevich, author

Evtyugin Vladimir Gennadevich, author

Mukhametzyanov Timur Anvarovich, author

Osin Yuriy Nikolaevich, author

Padnya Pavel Leonidovich, author

Stoykov Ivan Ivanovich, author

Authors, students KFU

Khripunova Irina Andreevna, author

Bibliographic description in the original language

Padnya P. L. Self-assembly of chiral fluorescent nanoparticles based on water-soluble L-tryptophan derivatives of p-tert-butylthiacalix[4]arene / P. L. Padnya, I. A. Khripunova, O. A. Mostovaya, T. A. Mukhametzyanov, V. G. Evtugyn, V. V. Vorobev, Yu. N. Osin, I. I. Stoikov // Beilstein Journal of Nanotechnology. - 2017. - � 8. - P. 1825-1835.

Annotation

New water-soluble tetra-substituted derivatives of p-tert-butylthiacalix[4]arene containing fragments of L-tryptophan in cone and 1,3-alternate conformations were obtained. It was shown that the resulting compounds form stable, positively charged aggregates of 86–134 nm in diameter in water at a concentration of 1 × 10−4 M as confirmed by dynamic light scattering, scanning electron microscopy and transmission electron microscopy. It was established that these aggregates are fluorescently active and chiral. A distinctive feature of the compounds is the pronounced dependence of their spectral (emission and chiroptical) properties on the polarity of the solvent and the length of the linker between the macrocyclic and fluorophore parts of the molecule.

Keywords

fluorescence, nanoparticles, self-assembly, thiacalixarene, tryptophan

The name of the journal

BEILSTEIN JOURNAL OF NANOTECHNOLOGY

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=174878&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Vorobev Vyacheslav Valerevich	ru_RU
dc.contributor.author	Evtyugin Vladimir Gennadevich	ru_RU
dc.contributor.author	Mukhametzyanov Timur Anvarovich	ru_RU
dc.contributor.author	Osin Yuriy Nikolaevich	ru_RU
dc.contributor.author	Padnya Pavel Leonidovich	ru_RU
dc.contributor.author	Stoykov Ivan Ivanovich	ru_RU
dc.contributor.author	Khripunova Irina Andreevna	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Padnya P. L. Self-assembly of chiral fluorescent nanoparticles based on water-soluble L-tryptophan derivatives of p-tert-butylthiacalix[4]arene / P. L. Padnya, I. A. Khripunova, O. A. Mostovaya, T. A. Mukhametzyanov, V. G. Evtugyn, V. V. Vorobev, Yu. N. Osin, I. I. Stoikov // Beilstein Journal of Nanotechnology. - 2017. - � 8. - P. 1825-1835.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=174878&p_lang=2	ru_RU
dc.description.abstract	BEILSTEIN JOURNAL OF NANOTECHNOLOGY	ru_RU
dc.description.abstract	New water-soluble tetra-substituted derivatives of p-tert-butylthiacalix[4]arene containing fragments of L-tryptophan in cone and 1,3-alternate conformations were obtained. It was shown that the resulting compounds form stable, positively charged aggregates of 86–134 nm in diameter in water at a concentration of 1 × 10−4 M as confirmed by dynamic light scattering, scanning electron microscopy and transmission electron microscopy. It was established that these aggregates are fluorescently active and chiral. A distinctive feature of the compounds is the pronounced dependence of their spectral (emission and chiroptical) properties on the polarity of the solvent and the length of the linker between the macrocyclic and fluorophore parts of the molecule.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	fluorescence	ru_RU
dc.subject	nanoparticles	ru_RU
dc.subject	self-assembly	ru_RU
dc.subject	thiacalixarene	ru_RU
dc.subject	tryptophan	ru_RU
dc.title	Self-assembly of chiral fluorescent nanoparticles based on water-soluble L-tryptophan derivatives of p-tert-butylthiacalix[4]arene	ru_RU
dc.type	Articles in international journals and collections	ru_RU