KFU. Card publication. 3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs

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3,3,6-TRIMETHYL-2-CHLOROCYCLOHEXENO[1,2-D]-1,2-OXAPHOSPHOL-4-ENE-2-OXIDE AS A CONVENIENT PRECURSOR FOR THE SYNTHESIS OF DIMEPHOSPHONE ANALOGS

Form of presentation

Articles in Russian journals and collections

Year of publication

2017

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Authors, employees of KFU

Mironov Vladimir Fedorovich, author

Nemtarev Andrey Vladimirovich, author

Authors, students KFU

Shemakhina Mariya Eduardovna, author

Bibliographic description in the original language

A.V.Nemtarev, M.E.Shemakhina, V.F.Mironov. 3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs. // Russ. J. Gen. Chem. 2017. Vol. 87. No. 4. P. 887-889. Doi 10.1134/S1070363217040387.

Annotation

A convenient approach to the synthesis of 3,3,6-trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-3-ene-2-oxide was developed based on the reaction of the naturally occurring terpenoketone pulegone with methyl dichlorophosphite. Treatment of oxaphospholene-2-oxide with water or ethanol yielded γ-phosphoryl ketones, dimephosphone analogs. The studied hydrolysis and alcoholysis processes differ in stereoselectivity.

Keywords

pulegone, methyl dichlorophosphite, phosphorylation, oxaphospholene, phosphoryl ketones, oxoalkylphosphonates

The name of the journal

Russian Journal of General Chemistry

URL

https://link.springer.com/article/10.1134/S1070363217040387

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=174862&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Mironov Vladimir Fedorovich	ru_RU
dc.contributor.author	Nemtarev Andrey Vladimirovich	ru_RU
dc.contributor.author	Shemakhina Mariya Eduardovna	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	A.V.Nemtarev, M.E.Shemakhina, V.F.Mironov. 3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs. // Russ. J. Gen. Chem. 2017. Vol. 87. No. 4. P. 887-889. Doi 10.1134/S1070363217040387.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=174862&p_lang=2	ru_RU
dc.description.abstract	Russian Journal of General Chemistry	ru_RU
dc.description.abstract	A convenient approach to the synthesis of 3,3,6-trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-3-ene-2-oxide was developed based on the reaction of the naturally occurring terpenoketone pulegone with methyl dichlorophosphite. Treatment of oxaphospholene-2-oxide with water or ethanol yielded γ-phosphoryl ketones, dimephosphone analogs. The studied hydrolysis and alcoholysis processes differ in stereoselectivity.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	pulegone	ru_RU
dc.subject	methyl dichlorophosphite	ru_RU
dc.subject	phosphorylation	ru_RU
dc.subject	oxaphospholene	ru_RU
dc.subject	phosphoryl ketones	ru_RU
dc.subject	oxoalkylphosphonates	ru_RU
dc.title	3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU