KFU. Card publication. Imines Derived from 4-Methyl-4-diphenylphosphorylpentan-2-one and Potassium Salts of Aminocarboxylic Acids

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FEDERAL UNIVERSITY

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IMINES DERIVED FROM 4-METHYL-4-DIPHENYLPHOSPHORYLPENTAN-2-ONE AND POTASSIUM SALTS OF AMINOCARBOXYLIC ACIDS

Form of presentation

Articles in Russian journals and collections

Year of publication

2017

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Authors, employees of KFU

Mironov Vladimir Fedorovich, author

Bibliographic description in the original language

M.N.Dimukhametov, V.F.Mironov, D.A.Tatarinov. Imines Derived from 4-Methyl-4-diphenylphosphorylpentan-2-one and Potassium Salts of Aminocarboxylic Acids. // Russ. J. Gen. Chem. 2017. Vol. 87. No. 4. P. 882-884. Doi 10.1134/S1070363217040363.

Annotation

An effective procedure for the preparation of imines based on 4-methyl-4-diphenylphosphorylpentan-2-one, aminoacetic, aminopropionic, and aminobutyric acids with yields of 90–95% was developed. Reaction of dimephosphone (4-methyl-4-dimethoxyphosphorilpentan-2-one) with potassium salts of these amino acids led to methylation of the carboxy group of the amino acid to form potassium salt of 2-methyl-4-oxopentylphosphonic acid methyl ester.

Keywords

γ-phosphoryl ketone, 4-phosphorylimine, dimephosphone, aminocarboxylic acid, dimephosphone potassium salt

The name of the journal

Russian Journal of General Chemistry

URL

https://link.springer.com/article/10.1134/S1070363217040363

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=174861&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Mironov Vladimir Fedorovich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	M.N.Dimukhametov, V.F.Mironov, D.A.Tatarinov. Imines Derived from 4-Methyl-4-diphenylphosphorylpentan-2-one and Potassium Salts of Aminocarboxylic Acids. // Russ. J. Gen. Chem. 2017. Vol. 87. No. 4. P. 882-884. Doi 10.1134/S1070363217040363.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=174861&p_lang=2	ru_RU
dc.description.abstract	Russian Journal of General Chemistry	ru_RU
dc.description.abstract	An effective procedure for the preparation of imines based on 4-methyl-4-diphenylphosphorylpentan-2-one, aminoacetic, aminopropionic, and aminobutyric acids with yields of 90–95% was developed. Reaction of dimephosphone (4-methyl-4-dimethoxyphosphorilpentan-2-one) with potassium salts of these amino acids led to methylation of the carboxy group of the amino acid to form potassium salt of 2-methyl-4-oxopentylphosphonic acid methyl ester.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	γ-phosphoryl ketone	ru_RU
dc.subject	4-phosphorylimine	ru_RU
dc.subject	dimephosphone	ru_RU
dc.subject	aminocarboxylic acid	ru_RU
dc.subject	dimephosphone potassium salt	ru_RU
dc.title	Imines Derived from 4-Methyl-4-diphenylphosphorylpentan-2-one and Potassium Salts of Aminocarboxylic Acids	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU