KFU. Card publication. Glassy carbon electrode modified with silver nanodendrites implemented in polylactide-thiacalix[4]arene copolymer for the electrochemical determination of tryptophan

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GLASSY CARBON ELECTRODE MODIFIED WITH SILVER NANODENDRITES IMPLEMENTED IN POLYLACTIDE-THIACALIX[4]ARENE COPOLYMER FOR THE ELECTROCHEMICAL DETERMINATION OF TRYPTOPHAN

Form of presentation

Articles in international journals and collections

Year of publication

2018

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Authors, employees of KFU

Evtyugin Gennadiy Arturovich, author

Porfireva Anna Veniaminovna, author

Stoykov Ivan Ivanovich, author

Bibliographic description in the original language

Porifreva A.V. Glassy carbon electrode modified with silver nanodendrites implemented in polylactide-thiacalix[4]arene copolymer for the electrochemical determination of tryptophan [Text] / A.V.Porfireva, V.V. Gorbatchuk, V.G. Evtugyn, I.I.Stoikov, G.A.Evtugyn // Electroanalysis. - 2018. - V.30. - P.641-649 .

Annotation

Glassy carbon electrode was modified by new polymeric materials obtained from oligolactides by cross-linking with tetracarboxylated thiacalix[4]arene in cone, partial cone and 1,3-alternate configurations and then silver was deposited by potential cycling in the pores of the polymer film. The modified electrode showed highly sensitive and selective signal toward tryptophan. The role of macrocycle configuration and conditions for Ag nanodendrites formation are described. Granulation of the polymer films caused by the macrocycles improves both the conditions for silver deposition and tryptophan determination. The electrochemical sensor developed makes it possible to determine from 0.1 to 100 mM of tryptophan with the limit of detection down to 0.03 mM. No interference with oxidation of other amino acids (phenylalanine, histidine, cysteine and tyrosine) was found.

Keywords

electrochemical sensor, voltammtetry, tryptophan determination, silver nanoparticles, polymer film

The name of the journal

ELECTROANALYSIS

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85037365394&doi=10.1002%2felan.201700638&partnerID=40&md5=0f57b4687be6d30a983b28805ddc8d97

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=171906&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Evtyugin Gennadiy Arturovich	ru_RU
dc.contributor.author	Porfireva Anna Veniaminovna	ru_RU
dc.contributor.author	Stoykov Ivan Ivanovich	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	Porifreva A.V. Glassy carbon electrode modified with silver nanodendrites implemented in polylactide-thiacalix[4]arene copolymer for the electrochemical determination of tryptophan [Text] / A.V.Porfireva, V.V. Gorbatchuk, V.G. Evtugyn, I.I.Stoikov, G.A.Evtugyn // Electroanalysis. - 2018. - V.30. - P.641-649 .	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=171906&p_lang=2	ru_RU
dc.description.abstract	ELECTROANALYSIS	ru_RU
dc.description.abstract	Glassy carbon electrode was modified by new polymeric materials obtained from oligolactides by cross-linking with tetracarboxylated thiacalix[4]arene in cone, partial cone and 1,3-alternate configurations and then silver was deposited by potential cycling in the pores of the polymer film. The modified electrode showed highly sensitive and selective signal toward tryptophan. The role of macrocycle configuration and conditions for Ag nanodendrites formation are described. Granulation of the polymer films caused by the macrocycles improves both the conditions for silver deposition and tryptophan determination. The electrochemical sensor developed makes it possible to determine from 0.1 to 100 mM of tryptophan with the limit of detection down to 0.03 mM. No interference with oxidation of other amino acids (phenylalanine, histidine, cysteine and tyrosine) was found.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	electrochemical sensor	ru_RU
dc.subject	voltammtetry	ru_RU
dc.subject	tryptophan determination	ru_RU
dc.subject	silver nanoparticles	ru_RU
dc.subject	polymer film	ru_RU
dc.title	Glassy carbon electrode modified with silver nanodendrites implemented in polylactide-thiacalix[4]arene copolymer for the electrochemical determination of tryptophan	ru_RU
dc.type	Articles in international journals and collections	ru_RU