Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
N,N-DIMETHYLDODECYLAMINE OXIDE SELF-ORGANIZATION IN THE PRESENCE OF LANTHANIDE IONS IN AQUEOUS AND AQUEOUS-DECANOL SOLUTIONS
Form of presentationArticles in Russian journals and collections
Year of publication2013
Языканглийский
  • Gnezdilov Oleg Ivanovich, author
  • Bibliographic description in the original language N.M. Selivanova, N,N-Dimethyldodecylamine Oxide Self-Organization in the Presence of Lanthanide Ions in Aqueous and Aqueous-Decanol Solutions/ N. M. Selivanova, A. I. Galeeva, A. A. Sukhanov , O. I. Gnezdilov, D. V. Chachkov, and Y. G. Galyametdinov// J. Phys. Chem. B.- 2013. – V.117 (17). – P. 5355–5364.
    Annotation The article represents the results of research in self-organization of new lanthanide systems in water−decanol medium. The systems are based on N,N-dimethyldodecylamine oxide, a zwitterionic surfactant. The study covers the complex formation of lanthanide ions with C12DMAO molecules and the influence of Ln(III) ions and medium composition on surfactant association in diluted solutions. The analysis of adsorption isotherms was carried out on the basis of the combination of Gibbs and Langmuir adsorption equations. The results were used to determine physicochemical properties and parameters of a monomolecular adsorption layer. The research objects were various lanthanide ions with identical coordination centers. A number of spectroscopic methods (UV, NMR self-diffusion, EPR, dynamic light scattering (DLS), and fluorescent analysis) were involved in the research for comparative estimations of molecular dynamics, critical micellizationconcentration, geometry, sizes, and aggregation numbers
    Keywords aggregation number, molecular dynamic, critical micellizationconcentration, NMR self-diffusion, EPR, dynamic light scattering, fluorescent analysis
    The name of the journal J PHYS CHEM B
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=163227&p_lang=2
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