KFU. Card publication. Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties

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ZINC(II) BIS(DIPYRROMETHENATE)S CRYSTAL SOLVATES WITH DIMETHYL SULFOXIDE COMPOSITION, STABILITY AND SPECTRAL-LUMINESCENT PROPERTIES

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Khodov Ilya Anatolevich, author

Bibliographic description in the original language

Ksenofontov A.A, Guseva G.B, Antinr E.V, Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties//Sensors and Actuators, B: Chemical. - 2017. - Vol.251, Is.. - P.858-868.

Annotation

This paper presents the results of UV/vis, fluorescence, FT-IR, DOSY, and DFT study of a novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]) with C60. It was found that zinc(II) bis(dipyrromethenate) forms stable supramolecular π-π-complexes ([Zn2L2(C60)4]) with C60. DFT calculations revealed stable complexation between [Zn2L2] and C60. The [Zn2L2(C60)4] LUMO energy levels are predominantly spread on the C60 unit and the HOMO energy levels are mainly spread on the [Zn2L2]. The photoinduced electron transfer testing by the substantial fluorescence quenching of the [Zn2L2] by non-covalent bonded C60 gives the positive result that shows prospects of the studying [Zn2L2(C60)4] as the active layers in solar energy conversion devices. 2018 Elsevier B.V.

Keywords

NMR, DOSY, Fluorescence, Fullerenes, Non-covalent, Supramolecular systems, Zinc(II) bis(dipyrromethenate)s.

The name of the journal

Sensors and Actuators, B: Chemical

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020047247&doi=10.1016%2fj.snb.2017.05.143&partnerID=40&md5=66d6bdc569b6e129750f4c01d77fe134

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=161672&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Khodov Ilya Anatolevich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Ksenofontov A.A, Guseva G.B, Antin� E.V, Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties//Sensors and Actuators, B: Chemical. - 2017. - Vol.251, Is.. - P.858-868.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=161672&p_lang=2	ru_RU
dc.description.abstract	Sensors and Actuators, B: Chemical	ru_RU
dc.description.abstract	This paper presents the results of UV/vis, fluorescence, FT-IR, DOSY, and DFT study of a novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]) with C60. It was found that zinc(II) bis(dipyrromethenate) forms stable supramolecular π-π-complexes ([Zn2L2(C60)4]) with C60. DFT calculations revealed stable complexation between [Zn2L2] and C60. The [Zn2L2(C60)4] LUMO energy levels are predominantly spread on the C60 unit and the HOMO energy levels are mainly spread on the [Zn2L2]. The photoinduced electron transfer testing by the substantial fluorescence quenching of the [Zn2L2] by non-covalent bonded C60 gives the positive result that shows prospects of the studying [Zn2L2(C60)4] as the active layers in solar energy conversion devices. 2018 Elsevier B.V.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	NMR	ru_RU
dc.subject	DOSY	ru_RU
dc.subject	Fluorescence	ru_RU
dc.subject	Fullerenes	ru_RU
dc.subject	Non-covalent	ru_RU
dc.subject	Supramolecular systems	ru_RU
dc.subject	Zinc(II) bis(dipyrromethenate)s.	ru_RU
dc.title	Zinc(II) bis(dipyrromethenate)s crystal solvates with dimethyl sulfoxide Composition, stability and spectral-luminescent properties	ru_RU
dc.type	Articles in international journals and collections	ru_RU