KFU. Card publication. Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin

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FEDERAL UNIVERSITY

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MOLECULAR RECOGNITION OF NITROGEN&NDASH;CONTAINING BASES BY ZN[5,15-BIS-(2,6-DODECYLOXYPHENYL)]PORPHYRIN

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Khodov Ilya Anatolevich, author

Bibliographic description in the original language

Maltceva O, Mamardashvili G, Khodov I, Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin //Supramolecular Chemistry. - 2017. - Vol.29, Is.5. - P.360-369.

Annotation

Supramolecular Chemistry

Keywords

NMR, 2D NMR, DOSY, binding ability, Porphyrin receptor, sensing device, spectrophotometric titration.

The name of the journal

Supramolecular Chemistry

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84990973232&partnerID=40&md5=83375a4c18f1ba08934ef7fca1786c62

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=159265&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Khodov Ilya Anatolevich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Maltceva O, Mamardashvili G, Khodov I, Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin //Supramolecular Chemistry. - 2017. - Vol.29, Is.5. - P.360-369.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=159265&p_lang=2	ru_RU
dc.description.abstract	Supramolecular Chemistry	ru_RU
dc.description.abstract	Supramolecular Chemistry	ru_RU
dc.description.abstract	By means of spectrophotometric titration and 1H NMR spectroscopy, the selective binding ability of the Zn-5,15-bis-(2,6-dodecyloxyphenyl)porphyrin towards nitrogen containing organic molecules of various nature has been studied. It has been found that the presence of long alkoxy substituents at the ortho-positions of the Zn-porphyrin phenyl rings prevents the axial coordination of tertiary amines and, conversely, creates favourable conditions for binding of a primary diamine due to the presence of additional binding sites, namely the oxygen atoms of the ortho–ortho'- dodecyloxy substituents of the meso phenyl groups. The formation of stable complexes with multiple binding sites has been confirmed by DFT quantum chemical calculations and two-dimensional NMR experiments.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	NMR	ru_RU
dc.subject	2D NMR	ru_RU
dc.subject	DOSY	ru_RU
dc.subject	binding ability	ru_RU
dc.subject	Porphyrin receptor	ru_RU
dc.subject	sensing device	ru_RU
dc.subject	spectrophotometric titration.	ru_RU
dc.title	Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin	ru_RU
dc.type	Articles in international journals and collections	ru_RU