Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
GAS/SOLID COMPLEXATION AND INCLUSION
Form of presentationInternational monographs
Year of publication2016
Языканглийский
  • Gatiatulin Askar Kamilevich, author
  • Gorbachuk Valeriy Vilenovich, author
  • Ziganshin Marat Akhmedovich, author
  • Bibliographic description in the original language V.V. Gorbatchuk Gas/Solid Complexation and Inclusion / V.V. Gorbatchuk, A.K. Gatiatulin, M.A. Ziganshin // Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2016
    Annotation Gas/solid complexation and inclusion are a versatile method used for gas and vapor sensing, storage and separation, preparation of inclusion compounds, and the study of structure?property relationships for host?guest crystals. Gas/solid complexation and inclusion may provide a genuine molecular recognition, which is not based on the ordinary lock-and-key concept. In this article, experimental procedures are reviewed, which are used to reach a permanent, virtual, or metastable host porosity, maximal selectivity, or reversibility of guest adsorption/inclusion, to enable inclusion of a target guest overcoming threshold by its thermodynamic activity and to make the host eligible for experimental measurements of thermodynamic inclusion parameters.
    Keywords Adsorption isotherm, Calixarene, Clathrate preparation, Cyclodextrin, Guest exchange, Hydration effect, Inclusion compound, Inclusion Gibbs energy, Inclusion irreversibility, Inclusion threshold, Molecular recognition, Phase transition, QCM sensor, Sorption cooperativity, Structure?property relationship
    URL http://www.sciencedirect.com/science/article/pii/B9780124095472124990
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=155052&p_lang=2

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