KFU. Card publication. Tracking of the formation of binuclear nickel complexes of [Ni2(m-O2PR1R2)2(bpy)4]Br2 type by ESI and MALDI mass spectrometry

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TRACKING OF THE FORMATION OF BINUCLEAR NICKEL COMPLEXES OF [NI2(M-O2PR1R2)2(BPY)4]BR2 TYPE BY ESI AND MALDI MASS SPECTROMETRY

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Yakhvarov Dmitriy Grigorevich, author

Authors, postgraduates KFU

Khusnuriyalova Aliya Fanusovna, postgraduate kfu

Bibliographic description in the original language

Polyhedron, 2017, 127, 302-306

Annotation

The formation of binuclear nickel complexes of type [Ni2(m-O2PR1R2)2(bpy)4]Br2, where R1 = H, R2 = phenyl (Ph), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp) or R1R2 = AOCH2CH(Et) NHCH(Ph)A; bpy = 2,20-bipyridine, in solution and their fragmentation behavior have been investigated by ESI and MALDI mass spectrometry. It was found that binuclear cationic fragments [Ni2(m-O2PR1R2)2(bpy)2Br]+ are characteristic ions displaying the formation of binuclear nickel(II) complexes in solution.

Keywords

Binuclear nickel complexes 2,20-Bipyridine Bridging ligands Organic phosphinic acids ESI and MALDI mass spectrometry

The name of the journal

POLYHEDRON

URL

https://doi.org/10.1016/j.poly.2017.02.005

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=154537&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Yakhvarov Dmitriy Grigorevich	ru_RU
dc.contributor.author	Khusnuriyalova Aliya Fanusovna	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Polyhedron, 2017, 127, 302-306	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=154537&p_lang=2	ru_RU
dc.description.abstract	POLYHEDRON	ru_RU
dc.description.abstract	The formation of binuclear nickel complexes of type [Ni2(m-O2PR1R2)2(bpy)4]Br2, where R1 = H, R2 = phenyl (Ph), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp) or R1R2 = AOCH2CH(Et) NHCH(Ph)A; bpy = 2,20-bipyridine, in solution and their fragmentation behavior have been investigated by ESI and MALDI mass spectrometry. It was found that binuclear cationic fragments [Ni2(m-O2PR1R2)2(bpy)2Br]+ are characteristic ions displaying the formation of binuclear nickel(II) complexes in solution.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Binuclear nickel complexes 2	ru_RU
dc.subject	20-Bipyridine Bridging ligands Organic phosphinic acids ESI and MALDI mass spectrometry	ru_RU
dc.title	Tracking of the formation of binuclear nickel complexes of [Ni2(m-O2PR1R2)2(bpy)4]Br2 type by ESI and MALDI mass spectrometry	ru_RU
dc.type	Articles in international journals and collections	ru_RU