Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
ELECTROCHEMICAL SYNTHESIS AND PROPERTIES OF ORGANONICKEL σ‑COMPLEXES
Form of presentationArticles in international journals and collections
Year of publication2014
Языкрусский
  • Khusnuriyalova Aliya Fanusovna, author
  • Yakhvarov Dmitriy Grigorevich, author
  • Khusnuriyalova Aliya Fanusovna, postgraduate kfu
  • Bibliographic description in the original language D.G.Yakhvarov, A.F.Khusnuriyalova, O.G.Sinyashin. Electrochemical Synthesis and Properties of Organonickel σ-Complexes. Organometallics. 2014, 33, 4574-4589.
    Annotation The organonickel complexes are organometallic compounds containing a Ni−C σ-bond (σ-complexes). These species are very reactive and have been mainly characterized as the intermediates of catalytic processes of cross coupling and homocoupling involving organic and elementoorganic substrates such as organic halides, chlorophosphines, unsaturated hydrocarbons, etc. Thus, only a limited number of these complexes have been isolated and characterized as the free stable species. Although the organonickel complexes have been known since the 1960s, the chemistry of these species is currently at the beginning stages of development. The interest of the researchers in this class of compounds has significantly increased over the past decade, resulting in a plethora of scientific papers published on this topic. At the same time, electrochemical methods have become more and more popular in modern synthetic chemistry, due to easy access to high reactive intermediates, including organometallic species,
    Keywords Organonickel sigma-complexes, electrochemistry, electrochemical synthesis, oligomerization, ethylene
    The name of the journal Organometallics
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=154534&p_lang=2

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