KFU. Card publication. Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride

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METHYLVIOLOGEN-MEDIATED ELECTROCHEMICAL SYNTHESIS OF SILVER NANOPARTICLES VIA THE REDUCTION OF AGCL NANOSPHERES STABILIZED BY CETYLTRIMETHYLAMMONIUM CHLORIDE

Form of presentation

Articles in international journals and collections

Year of publication

2017

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Authors, employees of KFU

Osin Yuriy Nikolaevich, author

Other authors

Fazleeva R. R., author

Gubaidullin A T, author

Nasretdinova G R., author

Yanilkin V. V., author

Bibliographic description in the original language

G. R. Nasretdinova Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride / G. R. Nasretdinova, R. R. Fazleeva, Yu. N. Osin, A. T. Gubaidullin, and V. V. Yanilkin // Russian Journal of Electrochemistry, 2017, Vol. 53, No. 1, pp. 25–38.

Annotation

Russian Journal of Electrochemistry

Keywords

electrosynthesis, nanoparticles, nanosphere, nanorod, silver, reduction, silver chloride, mediator, methylviologen, stabilizer, cetyltrimethylammonium chloride

The name of the journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=151755&p_lang=2

Resource files

File name	Size (MB)	Format
RJEL25.pdf	1,80	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Osin Yuriy Nikolaevich	ru_RU
dc.contributor.author	Fazleeva R. R.	ru_RU
dc.contributor.author	Gubaidullin A T	ru_RU
dc.contributor.author	Nasretdinova G R.	ru_RU
dc.contributor.author	Yanilkin V. V.	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	G. R. Nasretdinova Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride / G. R. Nasretdinova, R. R. Fazleeva, Yu. N. Osin, A. T. Gubaidullin, and V. V. Yanilkin // Russian Journal of Electrochemistry, 2017, Vol. 53, No. 1, pp. 25–38.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=151755&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF ELECTROCHEMISTRY	ru_RU
dc.description.abstract	Russian Journal of Electrochemistry	ru_RU
dc.description.abstract	Abstract—Efficient synthesis of silver nanoparticles stabilized by cetyltrimethylammonium cations (Ag@CTA+) is carried out in aqueous medium by methylviologen-mediated electroreduction of silver chloride nanospheres stabilized by surface-active CTA+ cations (AgCl@CTA+, diameter ~330 nm), on a glassy carbon electrode at potentials of the MV2+/MV?+ redox couple. The nanospheres AgCl@CTA+ can be reduced immediately on the electrode at a low rate and the resulting metal is deposited on the electrode. In the mediated reduction, the metal is not deposited on the cathode but the quantitative reduction of AgCl to Ag@CTA+ nanoparticles proceeds completely in solution volume at the theoretical charge. In aqueous solution, the nanoparticles are positively charged (electrokinetic (zeta) potential is +74.6 mV), their characteristic absorption maximum is at 423 nm and the average hydrodynamic diameter is 77 nm. Isolated Ag@CTACl nanoparticles have the size of 39 ? 15 nm.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	electrosynthesis	ru_RU
dc.subject	nanoparticles	ru_RU
dc.subject	nanosphere	ru_RU
dc.subject	nanorod	ru_RU
dc.subject	silver	ru_RU
dc.subject	reduction	ru_RU
dc.subject	silver chloride	ru_RU
dc.subject	mediator	ru_RU
dc.subject	methylviologen	ru_RU
dc.subject	stabilizer	ru_RU
dc.subject	cetyltrimethylammonium chloride	ru_RU
dc.title	Methylviologen-Mediated Electrochemical Synthesis of Silver Nanoparticles via the Reduction of AgCl Nanospheres Stabilized by Cetyltrimethylammonium Chloride	ru_RU
dc.type	Articles in international journals and collections	ru_RU