KFU. Card publication. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules

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CRYSTAL VIOLET DYE IN COMPLEXES WITH AMPHIPHILIC ANIONIC CALIX[4]RESORCINARENES: BINDING BY AGGREGATES AND INDIVIDUAL MOLECULES

Form of presentation

Articles in international journals and collections

Year of publication

2013

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Authors, employees of KFU

Konovalov Aleksandr Ivanovich, author

Mironova Diana Aleksandrovna, author

Morozova Yuliya Ernestovna, author

Other authors

Kazakova Ella Khatibovna, author

Muslinkina Liya Abdurakhimovna, author

Syakaev Viktor Vasilevich, author

Yanilkin Vitaliy Vasilevich, author

Bibliographic description in the original language

Mironova D.A. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules / D.A. Mironova, L. A. Muslinkina, V. V. Syakaev, J. E. Morozova, V. V. Yanilkin, A. I. Konovalov, E. Kh. Kazakova // J. Colloid Interf. Sci. - 2013. - V 407. - P. 148-154.

Annotation

Here, we report on a systematic study of six calix[4]resorcinarene macrocycles bearing eight carboxylic groups on the upper rim and four different lower rim substituents that are either aliphatic (2, 4, and 5) or alkylaromatic (1, 3, and 6). The macrocycles were studied in their individual aqueous solutions and in the presence of triphenylmethane dye crystal violet. It was found that binding of crystal violet with aggregated macrocycles shields it from the bulk of solution, preventing its discoloration under basic conditions and electrochemical reduction on the glassy carbon electrode. Most efficient shielding, reducing the rate of discoloration more than 173 times, as compared to solution with no macrocycle, was achieved with 6 forming aggregates of average 72 molecules in 0.1 mM solutions.

Keywords

Macrocycle, calix[4]resorcinarene, triphenylmethane dye, crystal violet, aggregation, NMR spectroscopy, UV?Vis, electrochemical reduction, fluorescence

The name of the journal

Journal of Colloid and Interface Science

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=139182&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Mironova Diana Aleksandrovna	ru_RU
dc.contributor.author	Morozova Yuliya Ernestovna	ru_RU
dc.contributor.author	Kazakova Ella Khatibovna	ru_RU
dc.contributor.author	Muslinkina Liya Abdurakhimovna	ru_RU
dc.contributor.author	Syakaev Viktor Vasilevich	ru_RU
dc.contributor.author	Yanilkin Vitaliy Vasilevich	ru_RU
dc.date.accessioned	2013-01-01T00:00:00Z	ru_RU
dc.date.available	2013-01-01T00:00:00Z	ru_RU
dc.date.issued	2013	ru_RU
dc.identifier.citation	Mironova D.A. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules / D.A. Mironova, L. A. Muslinkina, V. V. Syakaev, J. E. Morozova, V. V. Yanilkin, A. I. Konovalov, E. Kh. Kazakova // J. Colloid Interf. Sci. - 2013. - V 407. - P. 148-154.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=139182&p_lang=2	ru_RU
dc.description.abstract	Journal of Colloid and Interface Science	ru_RU
dc.description.abstract	Here, we report on a systematic study of six calix[4]resorcinarene macrocycles bearing eight carboxylic groups on the upper rim and four different lower rim substituents that are either aliphatic (2, 4, and 5) or alkylaromatic (1, 3, and 6). The macrocycles were studied in their individual aqueous solutions and in the presence of triphenylmethane dye crystal violet. It was found that binding of crystal violet with aggregated macrocycles shields it from the bulk of solution, preventing its discoloration under basic conditions and electrochemical reduction on the glassy carbon electrode. Most efficient shielding, reducing the rate of discoloration more than 173 times, as compared to solution with no macrocycle, was achieved with 6 forming aggregates of average 72 molecules in 0.1 mM solutions.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Macrocycle	ru_RU
dc.subject	calix[4]resorcinarene	ru_RU
dc.subject	triphenylmethane dye	ru_RU
dc.subject	crystal violet	ru_RU
dc.subject	aggregation	ru_RU
dc.subject	NMR spectroscopy	ru_RU
dc.subject	UV?Vis	ru_RU
dc.subject	electrochemical reduction	ru_RU
dc.subject	fluorescence	ru_RU
dc.title	Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules	ru_RU
dc.type	Articles in international journals and collections	ru_RU