KFU. Card publication. Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water

KAZAN
FEDERAL UNIVERSITY

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AMIDOAMINE CALIX[4]RESORCINARENE-BASED OLIGOMERS AND POLYMERS AS EFFICIENT SORBENTS OF AZO DYES FROM WATER

Form of presentation

Articles in international journals and collections

Year of publication

2015

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Authors, employees of KFU

Konovalov Aleksandr Ivanovich, author

Mironova Diana Aleksandrovna, author

Morozova Yuliya Ernestovna, author

Shalaeva Yana Viktorovna, author

Other authors

Kadirov Marsil Kakhirovich, author

Kazakova Ella Khatibovna, author

Nizameev Irek Rashatovich, author

Bibliographic description in the original language

Ya.V. Shalaeva, Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water / Ya.V. Shalaeva, Ju.E. Morozova, D.A. Mironova, E.Kh. Kazakova, M.T. Kadirov, I.R. Nizameev, A.I. Konovalov. // Supramol. Chem., 2015, 27, 595-605.

Annotation

The sorption behaviour of three kinds of macrocyclic sorbents – amidoamine tetradodecyloxyphenylencalix[4]resorcinarene 1 and tetramethyloxyphenylencalix[4]-resorcinarene 2 ; composition of calix[4]resorcinarene 1 1 2 , and novel P.1 and P.2 polymers with amidoamine calix[4]resorcinarene units towards three water-soluble azo dyes – methyl orange ( MO ), acid orange ( AO5 ) and Congo red ( CR ) was studied. All sorbents form supramolecular complexes with the aforesaid dyes. The best sorbent for MO was shown to be polymer P.1 , for the AO5 – composition 1 1 2 and for the CR – macrocycle 2, with high sorption capacities (373, 497 and 625 mg/g, respectively). The main factor in the binding of dyes by all studied sorbents proved to be surface electrostatic interactions. In addition to the Coulomb interactions, the most important factor for the polymers appeared to be the 'net' structure of the polymer with a high concentration of binding sites.

Keywords

calixresorcinarene; calixarene polymer; azo dye; sorbent; sorption capacity

The name of the journal

Supramolecular Chemistry

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=139099&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Mironova Diana Aleksandrovna	ru_RU
dc.contributor.author	Morozova Yuliya Ernestovna	ru_RU
dc.contributor.author	Shalaeva Yana Viktorovna	ru_RU
dc.contributor.author	Kadirov Marsil Kakhirovich	ru_RU
dc.contributor.author	Kazakova Ella Khatibovna	ru_RU
dc.contributor.author	Nizameev Irek Rashatovich	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Ya.V. Shalaeva, Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water / Ya.V. Shalaeva, Ju.E. Morozova, D.A. Mironova, E.Kh. Kazakova, M.T. Kadirov, I.R. Nizameev, A.I. Konovalov. // Supramol. Chem., 2015, 27, 595-605.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=139099&p_lang=2	ru_RU
dc.description.abstract	Supramolecular Chemistry	ru_RU
dc.description.abstract	The sorption behaviour of three kinds of macrocyclic sorbents – amidoamine tetradodecyloxyphenylencalix[4]resorcinarene 1 and tetramethyloxyphenylencalix[4]-resorcinarene 2 ; composition of calix[4]resorcinarene 1 1 2 , and novel P.1 and P.2 polymers with amidoamine calix[4]resorcinarene units towards three water-soluble azo dyes – methyl orange ( MO ), acid orange ( AO5 ) and Congo red ( CR ) was studied. All sorbents form supramolecular complexes with the aforesaid dyes. The best sorbent for MO was shown to be polymer P.1 , for the AO5 – composition 1 1 2 and for the CR – macrocycle 2, with high sorption capacities (373, 497 and 625 mg/g, respectively). The main factor in the binding of dyes by all studied sorbents proved to be surface electrostatic interactions. In addition to the Coulomb interactions, the most important factor for the polymers appeared to be the 'net' structure of the polymer with a high concentration of binding sites.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water	ru_RU
dc.type	Articles in international journals and collections	ru_RU