Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
COMPLEXES OF TETRAMETHYLENSULFONATOCALIX[4]RESORCINARENE AGGREGATES WITH METHYL ORANGE: INTERACTIONS WITH GUESTS AND DRIVING FORCE OF COLOR RESPONSE
Form of presentationArticles in international journals and collections
Year of publication2015
Языканглийский
  • Konovalov Aleksandr Ivanovich, author
  • Mironova Diana Aleksandrovna, author
  • Morozova Yuliya Ernestovna, author
  • Shalaeva Yana Viktorovna, author
  • Kadirov Marsil Kakhirovich, author
  • Kazakova Ella Khatibovna, author
  • Muslinkina Liya Abdurakhimovna, author
  • Nizameev Irek Rashatovich, author
  • Bibliographic description in the original language D.A. Mironova, Complexes of tetramethylensulfonatocalix[4]resorcinarene aggregates with methyl orange: Interactions with guests and driving force of color response / D.A. Mironova, L.A. Muslinkina, Ju.E. Morozova, Ya.V. Shalaeva, E.Kh. Kazakova, M.T. Kadyrov, I.R. Nizameev, A.I. Konovalov. // Colloids Surf., A, 2015, 468, 339–345.
    Annotation Here we report on the examination of 12 guests (G1–12) interactions with the aggregates of tetramethylensulfonated tetrapentylcalix[4]resorcinarene (H) and the azo-pH-indicator methyl orange (MO). At pH 4.2, addition of 40 and 100 equiv. of the guests to 40:1 H:MO solution resulted in deprotonation of the dye accompanied by UV/Vis spectra changes. Variation of MO deprotonation degree in the presence of G1–12 is discussed in relation to the guest interactions with the aggregated H and competition with the surface-bound MO.
    Keywords Macrocycle, Sulfonated calix[4]resorcinarene, Dye, Methyl orange, Aggregation, Spectrophotometry
    The name of the journal Colloids and Surfaces A: Physicochemical and Engineering Aspects
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=139096&p_lang=2

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