KFU. Card publication. Voltammetric sensing and quantification of eugenol using nonionic surfactant self-organized media

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FEDERAL UNIVERSITY

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VOLTAMMETRIC SENSING AND QUANTIFICATION OF EUGENOL USING NONIONIC SURFACTANT SELF-ORGANIZED MEDIA

Form of presentation

Articles in international journals and collections

Year of publication

2013

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Authors, employees of KFU

Budnikov German Konstantinovich, author

Ziganshina Endzhe Rishatovna, author

Ziyatdinova Guzel Kamilevna, author

Bibliographic description in the original language

Ziyatdinova, G. Voltammetric sensing and quantification of eugenol using nonionic surfactant self-organized media / G. Ziyatdinova, E. Ziganshina, H. Budnikov // Anal. Methods. - 2013. - V. 5. - No. 18. – P. 4750-4756.

Annotation

Triton X100 and Brij 35 based self-organized systems (at a concentration of 0.1 M) provide eugenol solubilization in water media. Eugenol is irreversibly oxidized on a glassy carbon electrode at 780 and 700 mV in 0.1 M LiClO4 in 0.1 M Triton X100 and Brij 35 micellar media, respectively. Electrochemicaloxidation of eugenol is a diffusion-controlled process and involves 2.0 electrons corresponding to the formation of o-quinone. The eugenol calibration graph is linear in the range 15-1230 uM with an estimated detection limit of 3.8 uM and a quantification limit of 12.6 uM. The addition of ethanol (10% v/v) to a 0.1 M Triton X100 micellar medium leads to the cathodic shift of eugenol oxidation potential of 50 mV. Under these conditions, the oxidation current linearly depends on the eugenol concentration in the range 0.02-1.0 mM with a detection limit of 0.01 mM. The preliminary extraction of eugenol in essential oils in a Triton X100 micellar medium has been carried out.

Keywords

Eugenol, surfactants, micellar media, cyclic voltammetry, food analysis, pharmaceutical analysis

The name of the journal

Analytical Methods

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84883240422&partnerID=40&md5=8886e0e5c400dcf9dc39848af7e6e340

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=134850&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Budnikov German Konstantinovich	ru_RU
dc.contributor.author	Ziganshina Endzhe Rishatovna	ru_RU
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.date.accessioned	2013-01-01T00:00:00Z	ru_RU
dc.date.available	2013-01-01T00:00:00Z	ru_RU
dc.date.issued	2013	ru_RU
dc.identifier.citation	Ziyatdinova, G. Voltammetric sensing and quantification of eugenol using nonionic surfactant self-organized media / G. Ziyatdinova, E. Ziganshina, H. Budnikov // Anal. Methods. - 2013. - V. 5. - No. 18. – P. 4750-4756.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=134850&p_lang=2	ru_RU
dc.description.abstract	Analytical Methods	ru_RU
dc.description.abstract	Triton X100 and Brij 35 based self-organized systems (at a concentration of 0.1 M) provide eugenol solubilization in water media. Eugenol is irreversibly oxidized on a glassy carbon electrode at 780 and 700 mV in 0.1 M LiClO4 in 0.1 M Triton X100 and Brij 35 micellar media, respectively. Electrochemicaloxidation of eugenol is a diffusion-controlled process and involves 2.0 electrons corresponding to the formation of o-quinone. The eugenol calibration graph is linear in the range 15-1230 uM with an estimated detection limit of 3.8 uM and a quantification limit of 12.6 uM. The addition of ethanol (10% v/v) to a 0.1 M Triton X100 micellar medium leads to the cathodic shift of eugenol oxidation potential of 50 mV. Under these conditions, the oxidation current linearly depends on the eugenol concentration in the range 0.02-1.0 mM with a detection limit of 0.01 mM. The preliminary extraction of eugenol in essential oils in a Triton X100 micellar medium has been carried out.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Eugenol	ru_RU
dc.subject	surfactants	ru_RU
dc.subject	micellar media	ru_RU
dc.subject	cyclic voltammetry	ru_RU
dc.subject	food analysis	ru_RU
dc.subject	pharmaceutical analysis	ru_RU
dc.title	Voltammetric sensing and quantification of eugenol using nonionic surfactant self-organized media	ru_RU
dc.type	Articles in international journals and collections	ru_RU